Looking for help with interpretation of FTIR transmission plot

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SUMMARY

The discussion centers around the interpretation of FTIR (Fourier Transform Infrared Spectroscopy) transmission plots from two separate labs analyzing an oil sample for contamination with an unspecified element X. One lab utilized transmission FTIR while the other employed absorption FTIR, leading to difficulties in comparing the results. Participants express skepticism regarding the identification of elemental contamination through FTIR, as the technique primarily detects molecular vibrations rather than elemental presence.

PREREQUISITES
  • Understanding of FTIR spectroscopy techniques, specifically transmission and absorption methods.
  • Familiarity with contamination analysis in oil samples.
  • Knowledge of molecular vs. elemental analysis in spectroscopy.
  • Basic principles of infrared spectroscopy and its applications in material analysis.
NEXT STEPS
  • Research the differences between transmission FTIR and absorption FTIR techniques.
  • Learn about the limitations of FTIR in identifying elemental contamination.
  • Explore alternative methods for analyzing elemental contamination in oils, such as ICP-MS (Inductively Coupled Plasma Mass Spectrometry).
  • Investigate the interpretation of FTIR spectra, focusing on identifying contamination peaks in ester-based oils.
USEFUL FOR

Chemists, laboratory technicians, and quality control analysts involved in oil analysis and contamination detection will benefit from this discussion.

CambridgeMart
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I've had an oil sample analysed by 2 separate labs; one of the labs came back with the analysis stating large amount of contamination with element X (sorry, I won't prejudice any responses with the element name for now). Unfortunately one lab used transmission FTIR and the other used absorption FTIR, so I personally can't equate the traces. Is anyone prepared to have a glance at the plot (poor copy unfortunately) below and ID the major contamination peaks (i.e. something you shouldn't normally find in an ester based oil?
TIA.

1630103907181.png
 
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CambridgeMart said:
contamination with element X
Something doesn't sound right, IR/FTIR doesn't deal with elements.

This is a bit homeworkish so I am moving the thread.
 

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