Reaction of SOCl2 with White Phosphorus: Product Analysis

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SUMMARY

The reaction of thionyl chloride (SOCl2) with white phosphorus produces several products, including phosphorus trichloride (PCl3), sulfur dichloride (SCl2), and phosphorus oxychloride (POCl3). The discussion emphasizes the challenge of memorizing inorganic reactions for exams, particularly for JEE (Joint Entrance Examination) preparation, where NCERT textbooks are deemed sufficient for the s-block and p-block elements. Participants express the need for effective memorization techniques and strategies to retain complex chemical reactions, highlighting the importance of understanding mechanisms over rote memorization.

PREREQUISITES
  • Understanding of inorganic chemistry principles
  • Familiarity with thionyl chloride (SOCl2) and its reactions
  • Knowledge of phosphorus compounds, specifically PCl3 and POCl3
  • Basic concepts of chemical reaction mechanisms
NEXT STEPS
  • Research effective memorization techniques for inorganic chemistry
  • Study the reaction mechanisms of thionyl chloride with various elements
  • Explore advanced inorganic chemistry textbooks beyond NCERT
  • Practice solving past JEE inorganic chemistry questions
USEFUL FOR

Students preparing for JEE, particularly those focusing on inorganic chemistry, educators seeking effective teaching strategies, and anyone interested in mastering chemical reaction mechanisms.

Raghav Gupta
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Homework Statement


The product formed in the reaction of SOCl2 with white phosphorus is
1. PCl3
2. SO2Cl2
3. SCl2
4. POCl3

Homework Equations


NA

The Attempt at a Solution


I can google that but I want to know that how can we know it intuitively or by ourselves?
It was asked in a test and in test, internet is not available.

There must be a way or then why it is asked in exam because there are many reactions in World ( may be infinite) and to rote memorize each of it may not be fruitful as we have to look at our retention power?
 
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These days I wouldn't know without checking some reference book.

At the same time there was definitely a moment (when I learned for an inorganic chemistry exam) that I remembered many such things.
 
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Borek said:
These days I wouldn't know without checking some reference book.

At the same time there was definitely a moment (when I learned for an inorganic chemistry exam) that I remembered many such things.
But in reference books also so many reactions are given maybe 100 or 150 for s - block. 300- 500 for p-block. They have done the balancing , written stoichometric coefficients, reactants and products.What is a clever way to learn?

Are the exams checking our rote memorization power by that?
 
It is in ncert page 177.
 
mooncrater said:
It is in ncert page 177.
HaHa know that. Can you answer my post 3?
 
For P block, s block and hydrogen only (and only) NCERT is sufficient for JEE (adv). For metallurgy, d-block, inorganic qualitative analysis (not in ncert) you need to go in deep.
 
mooncrater said:
For P block, s block and hydrogen only (and only) NCERT is sufficient for JEE (adv). For metallurgy, d-block, inorganic qualitative analysis (not in ncert) you need to go in deep.
Do you know every reaction given in NCERT of s block and p block?
 
Raghav Gupta said:
Do you know every reaction given in NCERT of s block and p block?
I need to revise the whole s block, p block and Hydrogen after which i can claim that(which I have not recently). But this is the minimal requirement that must be fulfilled to gain a score in inorganic.
 
What is a clever way of learning this reactions as I have asked in post 3 ?
You may have read that chapters earlier also in 11th grade but the thing is of retaining.
Some chapters we remember because of interest.
I was also trying to revise but it seems hard.
 
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There is no clever way. In a week, study and revise the whole inorganic twice, (nowadays you will need more time dedicated as we don't have time). Revise, revise, revise...
 
  • #11
Borek said:
These days I wouldn't know without checking some reference book.

At the same time there was definitely a moment (when I learned for an inorganic chemistry exam) that I remembered many such things.

Yes and there must be some reason beta-napthtol rings a bell, I must have known what it is used for once.:redface: :oldfrown:
 
  • #12
epenguin said:
Yes and there must be some reason beta-napthtol rings a bell, I must have known what it is used for once.:redface: :oldfrown:
So you have seen my other thread, involving β naphthol.:smile:
I was just asking if you people know some tricks to learn inorganic chemistry the clever way to retain all.

So I think the conclusion reached is don't give importance to these topics so much or if you have the power learn it all.( I hope epenguin will not put me in his blacklist.:rolleyes: )
In my opinion there must be a mechanism for these reactions or the people have not discovered that?
 
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