Trying to understand Hermitian adjoint proof

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    Hermitian Proof
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Discussion Overview

The discussion revolves around understanding a specific step in the proof of the Hermitian adjoint of the operator \(\hat{D}=\partial/\partial x\) within the context of quantum mechanics, particularly focusing on the behavior of wave functions at infinity and their implications for square integrability. The scope includes theoretical aspects of quantum mechanics and mathematical reasoning related to integration by parts.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant expresses confusion about a step in the proof related to the Hermitian adjoint and seeks clarification.
  • Another suggests that the term in question is a boundary term from integration by parts, which vanishes under certain conditions.
  • Some participants argue that square integrability does not necessarily imply that wave functions decay quickly enough at infinity, suggesting additional conditions may be required.
  • It is proposed that for wave functions to be square-integrable and well-defined, they should approach zero at infinity, although this is contested.
  • Participants discuss the relevance of physical boundary conditions and the implications for different types of wave functions, such as bound states versus free particles.
  • There is mention of using the Schwarz class of functions to justify the behavior of wave functions at infinity, with some suggesting that this approach simplifies the integration process.
  • One participant reflects on the need for physicists to understand distribution theory in relation to the topic.
  • A later reply indicates that viewing wave functions as distributions could provide a different perspective on the problem.
  • Another participant expresses gratitude for the discussion, indicating that their understanding has improved.

Areas of Agreement / Disagreement

Participants exhibit disagreement regarding the implications of square integrability and the conditions under which wave functions decay at infinity. While some suggest that certain conditions must be met, others propose that the discussion can be simplified by assuming wave functions belong to the Schwartz class. The discussion remains unresolved on these points.

Contextual Notes

Participants note that the discussion involves assumptions about the behavior of wave functions at infinity and the mathematical framework used to analyze them, including integration by parts and the properties of the Schwartz space.

Who May Find This Useful

This discussion may be useful for students and practitioners in quantum mechanics, particularly those interested in the mathematical foundations of operators and wave functions in Hilbert spaces.

Mary
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I'm currently reading the book Introductory Quantum Mechanics by Richard Liboff 4th edition.

I'm reading one of the proofs and I don't understand what is happening in one of the steps.

The problem is trying to find the Hermitian adjoint of the operator \hat{D}=\partial/\partialx defined in hilbert space

I have attached an image of the problem to this forum. The step I don't understand is circled. I understand where the last part (the - integral) comes in but the first part I do not understand. All I know is that it is equal to 0 and I don't know why. Thanks for any input.

I know this is probably just a simple math step I have probably forgotten about.
 

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Integration by parts?
 
The first part is the boundary term that comes from integration by parts. It vanishes because the physical wave-functions are taken to decay quickly enough while approaching infinity so as to be square-integrable (and thus normalizable).
 
WannabeNewton said:
It vanishes because the physical wave-functions are taken to decay quickly enough while approaching infinity so as to be square-integrable (and thus normalizable).

Square integrability does not imply that the functions decay quickly enough approach infinity. You'll need some special conditions on the wave functions.

But ok, these kind of physics problems don't need to be complicated by a mathematician, so I'll leave...
 
micromass said:
Square integrability does not imply that the functions decay quickly enough approach infinity. You'll need some special conditions on the wave functions.

But ok, these kind of physics problems don't need to be complicated by a mathematician, so I'll leave...
:biggrin:

It doesn't hurt for physicists to learn a little more...

In this case, I would have said that for ##\psi## to be square-integrable over the real line, and be such that ##\partial_x \psi## is well-defined everywhere (which is physically important for the momentum operator), then it's reasonable to deduce that
$$\lim_{|x|\to\infty} \psi(x) = 0 ~.$$Anything else needed?

-> Mary: Is your question now answered?
 
strangerep said:
:biggrin:

It doesn't hurt for physicists to learn a little more...

In this case, I would have said that for ##\psi## to be square-integrable over the real line, and be such that ##\partial_x \psi## is well-defined everywhere (which is physically important for the momentum operator), then it's reasonable to deduce that
$$\lim_{|x|\to\infty} \psi(x) = 0 ~.$$Anything else needed?

It's still not true then. We've actually been going through this in this thread: https://www.physicsforums.com/showthread.php?t=745413

In practice, can't you always choose ##\psi## in the Schwarz class? In that case, it would be true. Or perhaps if you demand ##xf(x)## and other to be square-integrable or something.
 
micromass said:
Square integrability does not imply that the functions decay quickly enough approach infinity.

I never said it did.
 
WannabeNewton said:
I never said it did.

Not sure why the square-integrable part was necessary then. Ah well, never mind :-p
 
micromass said:
Not sure why the square-integrable part was necessary then. Ah well, never mind :-p

The usual justification for why we take physical wave-functions to decay fast enough at infinity is so that we can ensure square-integrability through physical boundary conditions (at infinity) on the wave-functions. There are physically relevant cases where we have to consider wave-functions that don't decay fast enough e.g. free particles (plane waves) but we can get around this by using box normalization. Of course if the wave-functions correspond to bound states as opposed to scattering then boundary conditions are imposed on finite regions and may involve periodicity instead but that's not what the OP is considering.
 
  • #10
WannabeNewton said:
The usual justification for why we take physical wave-functions to decay fast enough at infinity is so that we can ensure square-integrability through physical boundary conditions (at infinity) on the wave-functions. There are physically relevant cases where we have to consider wave-functions that don't decay fast enough e.g. free particles (plane waves) but we can get around this by using box normalization. Of course if the wave-functions correspond to bound states as opposed to scattering then boundary conditions are imposed on finite regions and may involve periodicity instead but that's not what the OP is considering.

Of course, Liboff mentions none of that and just takes a generic ##\psi## in ##L^2##. Sigh...
 
  • #11
micromass said:
It's still not true then. We've actually been going through this in this thread: https://www.physicsforums.com/showthread.php?t=745413

In practice, can't you always choose ##\psi## in the Schwarz class? In that case, it would be true. Or perhaps if you demand ##xf(x)## and other to be square-integrable or something.
:redface:
I was trying to find a subset of the full Schwarz distribution theory framework that would answer the OP's question. But perhaps that's unwise. Physicists need to understand distribution theory.

So yes, I guess it's better (more direct) to answer the question in the way you suggest (Schwarz theory). :biggrin:
 
  • #12
strangerep said:
:redface:
I was trying to find a subset of the full Schwarz distribution theory framework that would answer the OP's question. But perhaps that's unwise. Physicists need to understand distribution theory.

So yes, I guess it's better (more direct) to answer the question in the way you suggest (Schwarz theory). :biggrin:

Hmm, interesting. You could always see ##\psi## as a distribution and then use the definition of distributional derivative (which then of course does not agree with the usual notions). It's a bit of a stretch, but I need to think about this.
 
  • #13
micromass said:
Hmm, interesting. You could always see ##\psi## as a distribution and then use the definition of distributional derivative (which then of course does not agree with the usual notions). It's a bit of a stretch, but I need to think about this.
Indeed. (Remember the conversations we've had in the past about Rigged Hilbert Space and QM?) But QFT people use the distributional (aka weak) derivative quite a lot, often without realizing that it has a name. :biggrin:
 
  • #14
I think for practical purposes the vector space of wavefunctions can always be taken as the Schwartz space, so that integration by parts with limits to infinity is reduced to 0.
 
  • #15
This makes a lot more sense now. Thanks for all of your help. I just couldn't accept that it was 0 and I wanted to know why. This is my first thread and its been so helpful!
 
  • #16
micromass said:
In practice, can't you always choose ##\psi## in the Schwarz class?

dextercioby said:
I think for practical purposes the vector space of wavefunctions can always be taken as the Schwartz space, so that integration by parts with limits to infinity is reduced to 0.

That's the way I tend to look at it.

Simply take it as a test function or for all practical purposes approximated by a test function and Bob's your uncle.

I used to really worry about such things but got a hold of the following nifty book that helped a lot:
https://www.amazon.com/dp/0521558905/?tag=pfamazon01-20

Thanks
Bill
 
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