Yeah that's right for the electric field, but you are wanting to know the force of repulsion between the two charges.
Since r << d you can treat these spheres as point charges. Simply plug the numbers into Coulomb's Law using q1=q2.
Here is a hint for the second part. You know the charge of the two spheres and you know the charge of an electron (1.602*10^-19 C) so how many of those would you need for it to equal the charge on each sphere.
From the force equation you gave you see you are multiplying q1 by q2 and since q1=q2 you essentially have q1^2.
So take the square root of the result you got and that will be your charge.
Your equation for the number is right so just fix up the charge value and you should be set.