Understanding an Approximation in Statistical Physics

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SUMMARY

The discussion focuses on the approximation in statistical physics represented by the equation $$(V - aw)(V - (N-a)w) \approx (V - Nw/2)^2$$, where ##V## is the volume, ##N## is the number of particles, and ##w## is the particle radius. Participants analyze the mathematical derivation and the significance of the factor ##1/2## in the approximation. The conclusion confirms that the approximation holds true to first order in ##w##, with the term ##\frac{N^2 w^2}{4}## classified as ##O(w^2)##, indicating its negligible impact in the context of the approximation.

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Arman777
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In a book that I am reading it says

$$(V - aw)(V - (N-a)w) \approx (V - Nw/2)^2$$

Where ##V## is the volume of the box, ##N## is the number of the particles and ##w## is the radius of the particle, where each particle is thought as hard spheres.

for ##a = [1, N-1]##
But I don't understand how this can be possible ? Any ideas
 
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\begin{align*}
(V - w)(V - (N-1)w) &= V^2 - wV - (N-1)wV + (N-1)w^2 \\

&= V^2 - NwV + O(w^2)
\end{align*}it is the same to first order in ##w##
 
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etotheipi said:
\begin{align*}
(V - w)(V - (N-1)w) &= V^2 - wV - (N-1)wV + (N-1)w^2 \\

&= V^2 - NwV + O(w^2)
\end{align*}it is the same to first order in ##w##
Thanks for your answer, however it seems that I made a mistake while typing. Can you also look my answer and maybe change yours as well ?
 
the factor ##a## you inserted in the edit doesn't change anything, they are still the same to order ##w## :smile:
 
etotheipi said:
the factor ##a## you inserted in the edit doesn't change anything, they are still the same to order ##w## :smile:
I see but I still cannot understand where that ##1/2## comes I mean its strange. It seems like its just invented from 'nothing'
 
Arman777 said:
I see but I still cannot understand where that ##1/2## comes I mean its strange

##(V - \frac{Nw}{2})^2 = V^2 - NwV + \frac{N^2 w^2}{4}##
multiplying out bracket
and ##\frac{N^2 w^2}{4} = O(w^2)##
 
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I guess I kind of understand..
 

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