Understanding the General Hamiltonian from the Schrödinger Equation

[joarb]

Is it possible to say that for a general Schrödinger equation

i \hbar \frac{\partial}{\partial t} | \psi (t) \rangle = \hat{H} | \psi (t) \rangle

one may obtain the general Hamiltonian operator

\hat{H} = i \hbar \frac{\partial}{\partial t}

Thanks!

 

[quetzalcoatl9]

Is it possible to say that for a general Schrödinger equation

i \hbar \frac{\partial}{\partial t} | \psi (t) \rangle = \hat{H} | \psi (t) \rangle

one may obtain the general Hamiltonian operator

\hat{H} = i \hbar \frac{\partial}{\partial t}

Thanks!

not quite, what you have written is actually the energy operator:

\hat{E} = i \hbar \frac{\partial}{\partial t}

the hamiltonian operator is:

\hat{H} = \frac{\hat{p}^2}{2m} + \hat{V}

 

[meopemuk]

Is it possible to say that for a general Schrödinger equation

i \hbar \frac{\partial}{\partial t} | \psi (t) \rangle = \hat{H} | \psi (t) \rangle

one may obtain the general Hamiltonian operator

\hat{H} = i \hbar \frac{\partial}{\partial t}

Thanks!

This observation is correct, but not very helpful.

Note that Schroedinger equation can be rewritten in an equivalent form

| \psi (t) \rangle = \exp(-\frac{i}{\hbar}\hat{H}t) | \psi (0) \rangle

where the time evolution operator \exp(-\frac{i}{\hbar}\hat{H}t) allows you to find the state vector |\psi (t) \rangle at any time if you know the state vector \psi (0) \rangle at time 0 and the Hamiltonian. This is the true significance of the Hamiltonian.

It is true that "operator" \frac{\partial}{\partial t} also formally describes the infinitesimal time evolution. However, in order to apply it to | \psi (0) \rangle you must already know the state vector at a later time | \psi (\Delta t) \rangle. So, you must know the solution of the (time evolution) problem, which you are trying to solve in the first place.

Eugene.

 

[quidamschwarz]

Hi Eugene,

you missed the t in your time evolution operator. It should be

| \psi (t) \rangle = \exp(-\frac{i}{\hbar}\,t\,\hat{H}) | \psi (0) \rangle \;,

where we assume, that the Hamiltonian is time-independent. In case of a time-dependent Hamiltonian, things get more complicated and the time evolution operater becomes (formally)

| \psi (t) \rangle = T\left(\exp(-\frac{i}{\hbar}\,\int_0^t\,\hat{H}(t')dt')\right) | \psi (0) \rangle \;,

where T is the time odering operator...

 

[meopemuk]

Hi Eugene,

you missed the t in your time evolution operator. It should be

| \psi (t) \rangle = \exp(-\frac{i}{\hbar}\,t\,\hat{H}) | \psi (0) \rangle \;,

where we assume, that the Hamiltonian is time-independent.

You are right about that. I corrected my formulas.

In case of a time-dependent Hamiltonian, things get more complicated and the time evolution operater becomes (formally)

| \psi (t) \rangle = T\left(\exp(-\frac{i}{\hbar}\,\int_0^t\,\hat{H}(t')dt')\right) | \psi (0) \rangle \;,

where T is the time odering operator...

You are right about that as well. I was thinking about isolated systems for which the Hamiltonian is always time-independent.

Eugene.

 

[belliott4488]

Isn't it also true that if you express the Hamiltonian in terms of the time derivative you are choosing a particular basis in which to express it? You could also choose to write it, for e.g., in the momentum basis. For that reason, I'd say that the Dirac notation is more general, being independent of a choice of basis.

 

[quidamschwarz]

Isn't it also true that if you express the Hamiltonian in terms of the time derivative you are choosing a particular basis in which to express it?

I don't think so. As far as I understand is the time parameter t in non-relativistic QM (what we are discussing here) something different as position and momentum. Well, physically this is trivial. What I mean is the following:

A quantum state is given as a vector in a Hilbert space. Which Hilbert space this is depends on your chosen perspective. In position representation the quantum state is represented by a function \psi:\mathbb{R}^3\to\mathbb{C}.

The time evolution of \psi is mathematically realized by a curve \psi_t in this Hilbert space, so time is "just" the parameter of this curve. Since the Hamiltonian is an operator on the Hilbert space, it can include derivatives in x (for position representation) but cannot include something like time-derivatives.

 

[joarb]

I want to thank all contributors for an illuminating discussion. :)