What is the average value of an observable in a quantum system?

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The average value of an observable in a quantum system is defined as the inner product of the state and the observable applied to the state, expressed as (ψ, Aψ). When the state is an eigenstate of the observable, the average value equals the eigenvalue, not a multiple of it. For non-eigenstates, the average value can still be computed using the expansion of the state in terms of the observable's eigenfunctions. This leads to the conclusion that the average energy can be determined using the expectation value formula <H> = ∑pnEn, where pn represents the probabilities derived from the coefficients in the expansion. The discussion emphasizes the importance of understanding the relationship between states and observables in quantum mechanics.
LagrangeEuler
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Why we define that average value of some observable ##\hat{A}## in state ##\psi## is
##(\psi,\hat{A}\psi)##
Why this isnot perhaps
##26(\psi,\hat{A}\psi)##?
 
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What if the state ψ was an eigenstate of the observable A?
 
In that case ##\hat{A}\psi=a\psi##,
so
##(\psi,\hat{A}\psi)=a##.
 
LagrangeEuler said:
In that case ##\hat{A}\psi=a\psi##,
so
##(\psi,\hat{A}\psi)=a##.
Right, where ##a## is the eigenvalue of the observable. Not ##26a##!
 
Tnx.
 
But still after I think. Ok. When the system is in some eigen- state ##\varphi_n##, we measure energy ##E_n##. So
##(\varphi_n,\hat{H}\varphi_n)=E_n##
but if system is in some other state, perhaps, ##\phi(x)## which is not eigenstate of observable ##\hat{H}## how I can be sure that average value of energy is
##(\phi(x),\hat{H}\phi(x))##?
 
The expectation value can be defined as <H>=∑npnEn. If you use Born's rule for the pn you get <ψ|H|ψ>.
 
LagrangeEuler said:
But still after I think. Ok. When the system is in some eigen- state ##\varphi_n##, we measure energy ##E_n##. So
##(\varphi_n,\hat{H}\varphi_n)=E_n##
but if system is in some other state, perhaps, ##\phi(x)## which is not eigenstate of observable ##\hat{H}## how I can be sure that average value of energy is
##(\phi(x),\hat{H}\phi(x))##?
You can express the general state ##\phi(x)## in terms of the eigenfunctions: ##\phi(x)## = ##a_1\varphi_1## + ##a_2\varphi_2## ...
where ##a_n^*a_n## represents the probability of measuring ##E_n##. Thus the average value will be ##(\phi(x),\hat{H}\phi(x))##.

(This is equivalent to what kith just said about using the Born rule.)
 

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