What Is the pH at Equivalence for a Weak Acid-Strong Base Titration?

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SUMMARY

The pH at equivalence for the titration of 25 mL of 0.1 M acetic acid (HOAc) with 0.15 M sodium hydroxide (NaOH) is determined by the concentration of the resulting sodium acetate (NaOAc) solution. At the equivalence point, the pH will be greater than 7 due to the presence of the conjugate base, sodium acetate. To calculate the exact pH, one must first determine the volume of NaOH required to reach equivalence, then use the Kb of sodium acetate to find the pH of the resulting solution.

PREREQUISITES
  • Understanding of weak acid-strong base titrations
  • Knowledge of stoichiometry and molarity calculations
  • Familiarity with the concept of conjugate bases and their Kb values
  • Ability to balance chemical equations
NEXT STEPS
  • Calculate the volume of NaOH needed for complete titration of 0.1 M HOAc
  • Learn how to calculate the Kb of sodium acetate from its Ka
  • Study the Henderson-Hasselbalch equation for buffer solutions
  • Explore the concept of pH at equivalence in other weak acid-strong base titrations
USEFUL FOR

Chemistry students, educators, and laboratory technicians involved in acid-base titrations and pH calculations.

monae
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25 mL of 0.1 M HOAc are titrated with 0.15 M NaOH. What is the pH at
equivalence?

I know that the pH at start will be greater than 1.0 and the pH at equivalence will be greater than 7 since its a titration of a weak acid and a strong base. But what I don't know is whether or not there is a way to solve this problem for the exact pH since the volume of NaOH is not given.
 
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can't you figure out the volume of NaOH, though?

write and balance the chemical eqn, and then use stoichiometric relationships to find the moles of NaOH. Divide this by the molarity (0.15 M) to get milliliters of NaOH.
 
monae said:
25 mL of 0.1 M HOAc are titrated with 0.15 M NaOH. What is the pH at
equivalence?

I know that the pH at start will be greater than 1.0 and the pH at equivalence will be greater than 7 since its a titration of a weak acid and a strong base. But what I don't know is whether or not there is a way to solve this problem for the exact pH since the volume of NaOH is not given.

The pH at equivalence point is the same as solution containing the equivalent concentration of sodium OAc. You can use the Kb of this conjugate base of the weak acid.
 

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