WURTZ REACTION Problem for alkanes using dry ether

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Discussion Overview

The discussion revolves around a homework problem related to the Wurtz reaction involving alkanes using dry ether and sodium. Participants explore the process of removing halogen atoms (Cl and Br) and the resulting compounds formed from the reaction.

Discussion Character

  • Homework-related, Exploratory, Technical explanation

Main Points Raised

  • One participant expresses uncertainty about how to remove the Cl and Br atoms in the Wurtz reaction.
  • Another participant clarifies that the free electrons involved are free radicals that will appear on the carbons attached to the halogens.
  • A participant claims to have derived Bicyclo[1.1.0]butane as the resulting compound from their attempts.
  • There is a confirmation from another participant that the derived compound is correct.

Areas of Agreement / Disagreement

There is a general agreement on the identification of free radicals and the resulting compound, but the initial uncertainty regarding the removal of halogens indicates that some aspects of the problem remain unresolved.

Contextual Notes

The discussion does not clarify the specific steps or mechanisms involved in the Wurtz reaction, nor does it address any assumptions about the starting materials or conditions required for the reaction.

Who May Find This Useful

Students studying organic chemistry, particularly those learning about reaction mechanisms and the Wurtz reaction.

agnibho
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Homework Statement


The problem given was to find out the resulting compound of this Wurtz reaction process using dry ether (Na).


Homework Equations


Now the main problem I faced was how to remove the Cl-atom and Br-atom. I am new to this so please help me out.

The Attempt at a Solution


I tried this out on my own. The dots are of course free electrons. Is this answer possible?? If not please help.
 

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You are on the right track but those free electrons (these are called free radicals) will appear on the carbons attached to the halogens. Can you proceed now?
 
Yeah that's right free radicals. I tried this and got Bicyclo[1.1.0]butane. I presume it's right, isn't it??
 

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agnibho said:
Yeah that's right free radicals. I tried this and got Bicyclo[1.1.0]butane. I presume it's right, isn't it??

Yep, you got it right! :smile:
 
Thanks a lot!
 

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