kalbuskj31
Sep7-10, 07:53 PM
1. The problem statement, all variables and given/known data
Calculate q, w, ΔH, ΔU, ΔS for the following problem: One mole of a monatomic ideal gas starting at 300K, and 10 atm, the gas freely expands into a vacuum to triple its volume.
2. Relevant equations
w = PΔV,
ΔU = q - w or Cv dT,
ΔH = ΔU + PΔV or Cp dT,
ΔS = qrev/T,
q = ???
3. The attempt at a solution
I'm having trouble understanding how the concept of the vacuum affects things such as temperature and pressure. Do temperature and/or pressure remain constant? I'm confused how to start this problem, since I can't identify the type of situation (adiabatic, isothermal, isobaric, etc.) this creates. Explanation on the effect a vacuum has would be very helpful.
Kyle
Calculate q, w, ΔH, ΔU, ΔS for the following problem: One mole of a monatomic ideal gas starting at 300K, and 10 atm, the gas freely expands into a vacuum to triple its volume.
2. Relevant equations
w = PΔV,
ΔU = q - w or Cv dT,
ΔH = ΔU + PΔV or Cp dT,
ΔS = qrev/T,
q = ???
3. The attempt at a solution
I'm having trouble understanding how the concept of the vacuum affects things such as temperature and pressure. Do temperature and/or pressure remain constant? I'm confused how to start this problem, since I can't identify the type of situation (adiabatic, isothermal, isobaric, etc.) this creates. Explanation on the effect a vacuum has would be very helpful.
Kyle