Chemistry Problem - Reaction Rates

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Homework Help Overview

The discussion revolves around a chemistry problem related to reaction rates and the Arrhenius equation. The original poster expresses confusion regarding the relationship between temperature changes and reaction rate increases, specifically questioning how to determine the factor by which the rate increases when the temperature changes from 118 C to 128 C.

Discussion Character

  • Exploratory, Assumption checking, Conceptual clarification

Approaches and Questions Raised

  • Participants discuss the use of the Arrhenius equation and the implications of temperature changes on reaction rates. Some question the sufficiency of the provided information to solve the problem, while others suggest making assumptions to progress.

Discussion Status

There is an ongoing exploration of the problem, with some participants offering guidance on how to approach the calculations. However, there is no explicit consensus on the assumptions needed to proceed, and confusion remains regarding the application of the Arrhenius equation.

Contextual Notes

Participants note that certain information, such as the activation energy (Ea), is not provided, which complicates the ability to solve the problem directly. The discussion reflects the challenges of working with incomplete data in chemistry problems.

Kawrae
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I know this isn't a physics problem, but it's driving me crazy because I can't figure it out.

>> The rate of a particular reaction doubles (2.0 X) when the temperature is increased from 25 C to 35 C. By what factor will the rate increase over the temperature interval of 118 C to 128 C? <<

I'm thinking I have to use the Arrhenius equation that says:
e^(k2/k1) = e^Ea/R(1/t1-1/t2)

But I'm not given all of the information I need to solve it, am I? I'm very confused... I read over the notes handed out in class and the section in the book that covers this topic and I still can't figure it out. :confused:
 
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this is not solvable unless you make some unrealistic assumtion..
 
Kawrae said:
I know this isn't a physics problem, but it's driving me crazy because I can't figure it out.

>> The rate of a particular reaction doubles (2.0 X) when the temperature is increased from 25 C to 35 C. By what factor will the rate increase over the temperature interval of 118 C to 128 C? <<

I'm thinking I have to use the Arrhenius equation that says:
e^(k2/k1) = e^Ea/R(1/t1-1/t2)

But I'm not given all of the information I need to solve it, am I? I'm very confused... I read over the notes handed out in class and the section in the book that covers this topic and I still can't figure it out. :confused:

Solve for Ea. You've got everything... k2/k1=2. you've got t1=25C and t2=35C (convert to K).


Then plug in Ea, t1=118C and t2=128C to solve for k2/k1 for the second situation.
 
Thanks I think I understand it now :smile: I was getting stuck with using k2/k1 being equal to 2... but since the rate is doubling, the k2 would have to be 2x larger. Thanks :D
 

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