Which Elements Have Unusual Electron Configurations?

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Discussion Overview

The discussion centers on identifying elements with unusual electron configurations that deviate from the expected patterns in the periodic table. It explores both specific examples of such elements and hypothetical scenarios involving changes to electron spin states.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant inquires about elements with electron configurations that differ from periodic table predictions, specifically mentioning the d-block.
  • Another participant proposes a hypothetical scenario where an additional spin state for electrons would alter the structure of the periodic table, suggesting changes in the number of columns in various blocks.
  • Several participants identify Copper and Silver as examples of elements with unusual electron configurations, noting their specific electron arrangements.
  • One participant highlights Palladium (Pd) as particularly unusual due to its lack of electrons in the s orbitals of its last shell, while also mentioning Chromium (Cr) as another example.
  • A later reply discusses the stability associated with half-full and fully filled 3d subshells, reiterating the unusual configurations of Chromium and Copper and providing their electron configurations in a more detailed format.

Areas of Agreement / Disagreement

Participants generally agree on the identification of specific elements with unusual electron configurations, such as Copper, Silver, and Chromium. However, there is no consensus on the broader implications of the hypothetical scenario regarding electron spin states and its impact on the periodic table structure.

Contextual Notes

Some claims regarding the stability of electron configurations and the energy levels of subshells are presented without detailed mathematical justification or exploration of underlying assumptions.

sarabellum02
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Which elements have electron configurations different from what the periodic table predicts? I have the d-block, but i don't know how/where to get the rest.


Suppose in another universe, everything about atomic structure is the same as in our universe BUT there are 3 possible spin states for an electron in an orbital(up, down, and side) instead of two. How would this change where the elements are in the periodic table?

thanks
 
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The "s" block would have 3 columns...The "p" block would have 9 columns,the "d" block would have 15 columns,the "f" block would have 21 columns...

Daniel.
 
I think the answer to what your asking is Copper and Silver

Copper is 1s2 2s2 2p6 3s2 3p6 4s1 3d10
Silver is 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s1 4d10
 
There are many more "anomalies" in the "d" block.I think Pd is the most unusual as it has no electron in the "s" orbitals o its last shell (5s0).

Daniel.
 
dextercioby said:
There are many more "anomalies" in the "d" block.I think Pd is the most unusual as it has no electron in the "s" orbitals o its last shell (5s0).
Agreed. And there is Chromium (4s1).

The Bob (2004 ©)
 
Apologies if this question has already been answered, but I'll give my answer anyway! It helps reconfirm chemical ideas in my head, and learning is good! :-p

both chromium and copper have unusual electron arrangements- due to the additional stability associated with a half full and completely full 3d subshell.

Cr= [AR]3d^5, 4S^1
Cu= [AR]3d^10, 4S^1

all the other elements in the d block (for period 4) have full 4d subshells as the 4d subshell has slightly lower energy associated with it in then the 3d subshell, and are filled first.

again, sorry, but its good revision for me, and I've got an exam soon on this!
 

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