What is the net charge for adp?

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Discussion Overview

The discussion revolves around the net charge of adenosine diphosphate (ADP) and the formal charge of an oxygen atom within its structure. Participants explore theoretical aspects, calculations related to formal charge, and the implications of binding with other elements.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant suggests that the net charge of ADP is zero, reasoning that it is a molecule.
  • Another participant proposes that the net charge of ADP is -3 and that ATP has a net charge of -4, expressing uncertainty about the formal charge.
  • A participant asks for clarification on what a formal charge is.
  • A definition of formal charge is provided, detailing the formula involving valence electrons, non-bonding electrons, and bonding electrons.
  • One participant calculates that if oxygen has 6 valence electrons and a certain arrangement of bonding and non-bonding electrons, its formal charge could be 0 or -2, depending on the total count.
  • Another participant expresses doubt about the -3 net charge for ADP, reiterating their expectation of a net charge of zero and calculating the formal charge of oxygen to be zero based on its electron configuration.
  • A later reply mentions that ADP has a net charge of zero but could lose 3 hydrogen atoms when binding with barium, resulting in a net charge of -3, suggesting that the -3 charge might be a natural state.

Areas of Agreement / Disagreement

Participants express differing views on the net charge of ADP, with some asserting it is zero and others proposing it is -3. The formal charge of oxygen also appears to be a point of contention, with calculations leading to different interpretations.

Contextual Notes

There are unresolved assumptions regarding the Lewis structure of ADP and the specific conditions under which the net charge may change when interacting with other elements.

Bailey
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what is the net charge for adp?(i'm guessing its zero since it is a molecule)

what is the formal charge of the oxygen(the one forming a double bond with phosphate)?

can someone give me a quick reply. thanx.
 
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I think:

Net charge ADP: -3
Net charge ATP: -4

I am not sure about the formal charge..
 
what is a formal charge?
 
Formal charge:

(# valence e-) - (# non-bonding e- + 1/2 # bonding e-)

you figure that one out :P
 
Actually, looking at it.. it is not so difficult.

Oxygen has 6 valence electrons.

Determine the number of nonbonding electrons and add to that the number of bonding electrons (half will belong to the O). If this number is 6, then O has a formal charge of 0. If this number is 8, O has a formal charge of -2.

But before being able to calculate anything, you'd have to write down the Lewis structure first.
 
thanx for reply guys.
but not really sure about the -3 for adp.
i'm expecting zero for net charge.
and the formal charge of oxygen to be zero( 2 lone pair, and a double bond)

2 lone pair + 1 double bond = 8e

2 lone pair + .5 double bond = 6e

Formal charge of oxygen:

(# valence e-) - (# non-bonding e- + 1/2 # bonding e-)

(6 valence e) - (4 non-bonding e + .5(4 bonding e)) = 0
 
adp have a net charge of zero. but when it bind with Ba (i think is Ba , not exactly sure), it will lose 3H, hence it will then have a net charge of -3.

i think the net charge of -3 probably is one that exist in nature.
 

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