What is the material that has the highest boiling point?

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Discussion Overview

The discussion revolves around identifying the material with the highest boiling point, with a focus on materials relevant to evaporation processes in a laboratory setting. Participants explore various materials, including metals and ceramics, and their properties related to boiling and evaporation.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests that there must be a material on Earth with a higher boiling point than tungsten, possibly a ceramic used in aerospace applications.
  • Another participant mentions that many carbides, particularly those of zirconium, niobium, and tantalum, are high boiling materials, and highlights a material called Zircar that melts at nearly 5000°C.
  • Graphite and diamond are also proposed as materials to consider due to their high thermal stability.
  • A cautionary note is raised about the risks of contamination when using different materials in an evaporator, emphasizing the importance of material compatibility.
  • Rhenium is identified as having the highest boiling point among elements, with a boiling point of 5869 K (5596 °C), although it is suggested that some carbides might have higher boiling points.
  • One participant clarifies that materials can be evaporated without reaching their boiling point, as long as sufficient vapor pressure is achieved.
  • Another participant confirms the use of a mini e-beam evaporator and acknowledges the importance of using resistant crucibles and avoiding contamination.

Areas of Agreement / Disagreement

Participants express differing views on which material has the highest boiling point, with no consensus reached. There is agreement on the importance of avoiding contamination in evaporation processes.

Contextual Notes

Some discussions involve assumptions about material properties and the conditions under which evaporation occurs, which may not be fully resolved. The relationship between boiling and evaporation is noted to be nuanced, particularly in different languages.

Nissen, Søren Rune
Me and a colleague are looking (Just for the fun of it) for the material which has the highest boiling point. Our evaporater, which we use to boil palladium, claims that since it can boil Wolfram/Tungsten, it can evaporate anything. Material physics like this is not my strong suit, but surely there must be a material on Earth that has a higher boiling point? Possibly some ceramic material like they use on the space shuttle?
 
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I'm not real familiar with e-beam evaporators (I'm guessing that's what you have), but do you keep the tunsten in a crucible ? If you do, then your crucible material probably is one solution.

In any case, here's an additional list for you to look through and double check :

Many carbides are very high melting and hence high boiling materials (particularly carbides of zirconium, niobium and tantalum). A reasonably new material known as Zircar (or zirconia felt) melts at nearly 5000C (this is possibly very close to that "highest boiling point" material that you are looking for). And not to leave out the obvious, check out graphite and diamond !

You do know that you can successfully evaporate a material without ever reaching the boiling point. All you need is sufficient vapor pressure at the working T,P.
 
As a cautionary note : it's not wise to put unwanted materials in your evaporator, just for the fun of it. Contamination could easily lead to the failure of every future material/device/sample that gets made in the same evaporator, because of a material incompatibility (accidental doping).
 
Last edited:
Rhenium has the highest boiling point of the elements - Boiling point [/K]: 5869 [or 5596 °C (10105 °F)] (liquid range: 2410 K)

www.webelements.com

Possibly one of the carbides has a slightly higher boiling point.

Gokul gives some good advice - be careful what you put in your equipment.

Usually one volatizes (or vaporize) high temperature materials in an inductively coupled plasma (ICP). There is nothing solid in which such material can be contained (since it has the highest boiling point). So such a state is transient, at least in earthly environments.
 
Gokul: Yes, it's a mini e-beam evaporator, an EGCO4.

And, obviously, the crucible is resistant. Answer right under my nose the whole time.

And I'm not going to put anything but palladium in the evaporator, I know of the contamination dangers. Also of the fact that you don't need to bring it to the boiling point. There's a bit of translation trouble there, "evaporate" and "boil" are pretty much synonyms in danish.

Thank you, both of you.
 

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