I know quite a bit about electrons and quarks:) I guess "structureless" is pretty ambiguous. I took structureless to mean without any internal quantum numbers, and spin is internal in the sense that it is intrinsic. I've never seen an electron called a "structureless" particle, only "fundamental" particle. It would be nice to see some context, I guess.
And 5/2 isn't an allowed spin for fundamental particles:)