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Enthalpy and Heat State Functions |
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| Feb24-12, 07:23 PM | #1 |
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Enthalpy and Heat State Functions
I'm sure this topic has been asked before so I'd be happy if you'd just direct me to the thread.
I know U+PV=H and if the only work done is PV work then H=q-P∆V+P∆V=q. And I know that pressure must be constant. I also know that a state function is a function where the value of the function only depends on the change between the last and first states. I have 2 questions. 1. If pressure were not constant wouldn't the PV work=0 and enthalpy would still equal q? 2. I understand why enthalpy is a state function. The heat lost or gained only depends on the change between the first and last states. If enthalpy always equals q then why isn't q a state function? For example if 2 reactions happened one released 20 kJ of heat and one absorbed 10 kJ of heat the change in q or the heat lost or gained in the system is -20 kj + 10 kj =10 kJ lost. I feel like my reasoning is probably off somewhere. Can someone help me please? |
| Feb25-12, 11:58 AM | #2 |
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Only mechanical work (dU = δQ - pdV) dH = δQ + Vdp If p=constant dH|p = δQ|p |
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| chemistry, enthalpy, heat, state function, thermodynamics |
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