How Does Isothermal Expansion Affect Work and Entropy in an Ideal Gas?

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SUMMARY

The discussion focuses on the calculation of work and entropy change during isothermal expansion of an ideal gas at Standard Temperature and Pressure (STP). The work done (W) can be calculated using the formula W = nRTln(V2/V1), where n is the number of moles, R is the gas constant, T is the temperature (273.15K), and V2 and V1 are the final and initial volumes, respectively. The change in entropy (ΔS) is calculated using ΔS = nRln(V2/V1), with a reported change of 3.7 J/K for 1 mol of ideal gas. However, the final volume or pressure is necessary to determine the exact work done.

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  • Understanding of ideal gas laws
  • Familiarity with thermodynamic concepts such as work and entropy
  • Knowledge of Standard Temperature and Pressure (STP) conditions
  • Basic proficiency in logarithmic calculations
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This discussion is beneficial for students and professionals in physics and chemistry, particularly those studying thermodynamics, as well as engineers and researchers working with gas systems and energy transfer.

Dx
Hiya!
A container of ideal gas at STP undergoes an isothermal expansion and its entrop changes by 3.7JdegreeK. How much work does it do?

i have [del]S = [del]S_s + [del]S_env >= 0.

I am confused 1 mol of iseal gas at STP has vol = 22.4L but i usaully given themass also to find Q unless its 37. / 22.4 which gives me 1.0 x 10^3 J.
is this correct?
Thanks!
Dx :wink:
 
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remember isothermal so [del]U = 0

dS = dQ/T

enough there to get the answer.
 


Hi there!

To calculate the work done in an isothermal expansion, we can use the formula W = nRTln(V2/V1), where n is the number of moles of gas, R is the gas constant, T is the temperature in Kelvin, and V2 and V1 are the final and initial volumes, respectively. Since the gas is at STP, we know that the temperature is 273.15K and the initial volume is 22.4L for 1 mol of gas. However, we do not have enough information to calculate the final volume, so we cannot determine the work done. We would need to know the final volume or pressure in order to calculate the work done.

As for the entropy change, your calculation seems to be correct. The change in entropy is given by [delta]S = nRln(V2/V1), where n is the number of moles of gas, R is the gas constant, and V2 and V1 are the final and initial volumes, respectively. Using the values for STP, we get [delta]S = 1 mol x 8.314 J/mol K x ln(V2/22.4L) = 3.7 J/K.

I hope this helps clarify things for you! Let me know if you have any other questions. :)
 

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