Surface area vs rate of evaporation

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Discussion Overview

The discussion revolves around the relationship between surface area and the rate of evaporation in two vessels containing the same liquid and subjected to identical heating conditions. Participants explore the differences between boiling and evaporation, and whether a formula exists to quantify the effect of surface area on evaporation rates.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether the vessel with a larger surface area will evaporate liquid faster than one with a smaller surface area, given identical conditions.
  • Another participant asserts that if the same amount of heat is supplied to both vessels, the rate of evaporation will be the same, although surface tension may have a minor impact.
  • A clarification is made distinguishing boiling from evaporation, stating that boiling occurs when vapor pressure exceeds atmospheric pressure, while evaporation is a surface phenomenon.
  • It is suggested that water will evaporate faster from a vessel with a larger surface area when both vessels are heated to below boiling point, requiring more heat input to maintain temperature.
  • A participant seeks a specific name or formula for the relationship between evaporation rate and surface area.
  • Another participant responds that evaporation is proportional to surface area, with the proportionality influenced by the properties of the liquid and temperature.
  • A reference to "Langmuir" is provided, possibly indicating a relevant model or theory related to the discussion.

Areas of Agreement / Disagreement

Participants express differing views on the relationship between surface area and evaporation rates, with some asserting that surface area affects evaporation while others argue that heat input equalizes the rates. The discussion remains unresolved regarding the existence of a specific formula or named relationship.

Contextual Notes

Participants note the importance of distinguishing between boiling and evaporation, and the discussion includes assumptions about heat input and the properties of the liquid, which may affect the conclusions drawn.

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Two vessels of the same volume, in the same location and open to the atmosphere. One is tall and of a small diameter, the other is short and is of a larger diameter.

Each vessel supplied with an identical heat source. Each vessel filled with an equal volume of an identical liquid.

The goal is to reduce the volume of the liquid in both vessels by 1/2.

I know it will take exactly the same amount of energy to bring each vessel to the boil.

The question is will the vessel with the larger surface area evaporate the liquid faster than the smaller one?

Is there a formula or known and named relationship the would allow me to say "If I doubled the area available to evaporation, I would see an X increase in the rate of evaporation."?
 
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If the same amount of heat is going into both fluids at the same rates, then both containers will have the same rate of evaporation. Surface tension might play a small role but I would presume it to be negligible.
 
Important clarification, though: boiling and evaporation are not quite the same thing. Boiling is specifically the internal vaporization of a liquid due to adding heat to bring the vapor pressure above atmospheric pressure. Evaporation, typically, is a surface effect where water is vaporized due to the vapor pressure at the surface's temperature being above the vapor pressure of water in the air.

So since the two concepts were mixed and matched, I'm going to proivde two answers:
-Water will boil (roughly) equally fast in two different shaped vessels given the same heat input.
-Water will evaporate faster from a vessel with more surface area exosed to the atmosphere than from one with less surface area exposed to the atmosphere.

This also means that if you heat the water up to slightly less than the boiling point, the one with more surface area will evaporate faster and as a result, keeping the temperature steady will require more heat input.
 
Thanks for the clarifications. I appreciate it, and I think I got it.

Now, does this evaporation rate vs surface area relationship have a name or a formula?
 
Simply that evaporation is proportional to surface area. The proportionality depends upon things such as the properties of the specific liquid and the temperature.
 
See "Langmuir."
 

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