How Do You Find the Empirical Formula of a Nickel or Dime?

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Discussion Overview

The discussion revolves around the methods for determining the empirical formula of a nickel or dime, focusing on the composition and analysis techniques applicable to these coins. Participants explore various approaches, including elemental analysis and the challenges posed by the non-molecular nature of the materials.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant suggests that knowing the composition is essential before calculating the empirical formula, questioning whether percentages of each element need to be determined first.
  • Another participant proposes sending a sample for elemental analysis to obtain the necessary data for determining the formula.
  • A different viewpoint emphasizes that a nickel or dime is not a molecular solid, indicating that the term "empirical formula" may not apply in the traditional sense.
  • Several methods for elemental analysis are mentioned, including XRD, XRF, SIMS, and NMR, as viable techniques for determining composition.
  • One participant notes that the coins are not pure substances and may contain various elements in differing proportions, complicating the determination of a consistent empirical formula.
  • Another response details a potential analytical procedure involving solubilization and atomic absorption spectrometry to analyze the coin's composition.

Areas of Agreement / Disagreement

Participants express differing views on the applicability of the empirical formula to coins, with some arguing that the concept does not fit due to the complexity of their composition. There is no consensus on a single method or approach to determine the empirical formula.

Contextual Notes

The discussion highlights limitations related to the non-pure nature of the materials and the complexity of their compositions, which may vary significantly between individual coins.

babbagee
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I was just wondering how would i go about finding the emperical formula for an nickel or dime. I am not about to go and do this but i was just wondering what would be the steps. Would i have to know what it is composed of first and then find out the precentages of each element in the nickel or dime, or there some other way.

Thanks
 
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I'm pretty sure you could just send out a sample of the nickel or dime for elemental analysis, and you will be able to determine the formula when you get your results back.
 
First of all, the nickel or dime is not a molecular solid, so it's constituent elements will not be in some simple whole number ratio. I'm only saying this because of your use of 'empirical formula'.

The composition of a nickel or dime is not too hard to determine by spectroscopic analysis. XRD (X-Ray Diffraction), XRF (X-Ray Fluorescence), SIMS (Secondary Ion Mass Spectrometry), and NMR are some of the methods used for elemental analysis.
 
You need to ask an analytical chemist for help.
 
To find the empirical formula of some molecule, you would need the percent composition (by mass) of the elements that make up that molecule. To figure out the molecular formula, you would need all that plus the molar mass of the sample. In you case this can't be done because a nickel or dime are made of elements, not molecules.
 
In this case it can't be done because the substance isn't pure, it's a composition of different things. It can be 90% Ni, 5% Zn, 5% whatever. Or it can be 87% Ni...and so on. This does not imply that the nickel itself is a pure substance. To use the empirical formula would imply that NiZn3Al2 (for example) would be consistently found throughout the nickel or dime. This is not the case. The interior of the dime might be Ni, the outside might be Zn, etc. Or maybe the inside is an alloy or something. In either case the ENITRE dime is NOT made of one particular pure substance.
 
Composition of nickel or dime

Rajvirnijjar said:
I was just wondering how would i go about finding the emperical formula for an nickel or dime. I am not about to go and do this but i was just wondering what would be the steps. Would i have to know what it is composed of first and then find out the precentages of each element in the nickel or dime, or there some other way.

Thanks

Hello,

Your query is a daily concern of an analytical chemist, I think. The first step should be a solubilization/or digestion step (of pre-weighed sample ) with very strong acidic mixtures such as HNO3, HCl, H2SO4, and HClO4, etc. The resultant solution will contain all of the inorganic substances in it; the organic ones (if present) should be treated with an alternative way such as solid-liquid extraction, soxhlet extraction, and so on.

The acidic solution is diluted to a 100-fold of the original sample, and analyzed by atomic absorption spectrometry. This method will give quantitative results such as ppm, ppb, etc. With this data, you can calculate the first concentration in the first solution; and then calculate the overall ionic content of the sample analyzed.

Regards
chem_tr
 

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