Why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

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Discussion Overview

The discussion revolves around the question of why the time derivative of the expectation value of the position-momentum product, , is zero for a stationary state in quantum mechanics, as stated in Liboff's "Introductory Quantum Mechanics." Participants explore the implications of the Heisenberg equation of motion and the definition of stationary states.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants reference the Heisenberg equation of motion for operators, which states dO/dt=(i/hbar)[H,O]+∂O/∂t, noting that since x and p have no explicit time dependence, the partial derivative is zero.
  • Others argue that the expectation value for stationary states does not evolve in time, leading to the conclusion that d/dt = 0.
  • A participant mentions that while the expectation value is constant for stationary states, removing the brackets does not imply that the operator itself has a zero time derivative.

Areas of Agreement / Disagreement

Participants generally agree on the application of the Heisenberg equation and the definition of stationary states, but there is some uncertainty regarding the implications of removing the expectation value brackets and whether that leads to a zero time derivative.

Contextual Notes

Discussion includes references to specific texts and prior knowledge, indicating that some participants are revisiting concepts after a significant time lapse. There is an acknowledgment of the need for clarity regarding the definitions and implications of stationary states in quantum mechanics.

pmb
There's a problem in Liboff's text "Introductory Quantum Mechanics - 3rd Ed."

On page 176 problem 6.12 states

"A particle moving in one dimension interacts with a potential V(x). In a stationary state of this system show that

(1/2) <x dV/dx > = <T>

where T = p^2/2m is the kinetic energy of the particle."

Liboff gives the answer but starts off with

"In a stationary state,

d<xp>/dt = (i/hbar)<[H,xp]> = 0
..."

Why? I.e. why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

Pete
 
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Originally posted by pmb
Why? I.e. why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

Look up the Heisenberg equation of motion for operators. The equation is:

dO/dt=(i/hbar)[H,O]+&part;O/&part;t

for any operator O. Evidently, x and p have no explicit time dependence in your problem so the partial with respect to t is zero. The derivation should be in your book, but the basic reason is that the Hamiltonian is the generator of time translations, and so you would expect it to be closely associated with the time evolution of operators.
 


Originally posted by Tom
Look up the Heisenberg equation of motion for operators. The equation is:

dO/dt=(i/hbar)[H,O]+&part;O/&part;t

for any operator O. Evidently, x and p have no explicit time dependence in your problem so the partial with respect to t is zero. The derivation should be in your book, but the basic reason is that the Hamiltonian is the generator of time translations, and so you would expect it to be closely associated with the time evolution of operators.

{Note: Liboff is is a quick review for me for the summer so I've bneen through this before - but 10 years ago. We used Cohen-Tannoudji in grad school - both semesters - so I'm brushing up to jump into that}

What you've said is in a way related to this section in a certain sense - this was a section on the relation

d<A>/dt = <i/hbar [H,A] +&part;A/&part;t>

In this case A = xp. Th partial drops out and we're left with


d<ap>/dt = i/hbar <[H,xp]>

But Liboff sets that to zero - why?

Pete
 


Originally posted by pmb
d<ap>/dt = i/hbar <[H,xp]>

But Liboff sets that to zero - why?

OK, now I understand your question. He sets it to zero because you are looking at an expecation value, which for stationary states does not evolve in time (by definition of "stationary state"). Take away the < > brackets, and you do not necessarily get zero.
 


Originally posted by Tom
OK, now I understand your question. He sets it to zero because you are looking at an expecation value, which for stationary states does not evolve in time (by definition of "stationary state"). Take away the < > brackets, and you do not necessarily get zero.
'

Ahhh! The expectation for any operator for a stationary state is a constant in time!

Okay - Thanks. I get it now. Duh! :-) I can't see why I missed that now. Thanks Tom

Pete
 

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