Calculating Ionic Radius of Chloride Ion in LiCl (NaCl Structure)

In summary, a unit cell is the smallest repeating unit in a crystal lattice and is important in understanding the structure and properties of a crystal. It can be determined experimentally through techniques such as X-ray crystallography and there are seven different types based on the angles and lengths of their sides. The unit cell is also the basic building block of the crystal lattice, with its size and shape determining the overall symmetry and properties of the crystal.
  • #1
johncena
131
1
Q.The unit cube length of LiCl (NaCl structure) is 5.14 amstrong . Assuming anion-anion contact, calculate the ionic radius for chloride ion.

How to assume anion-anion contact ? Can anyone help with a 3D figure?
 
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  • #2
The NaCl structure is very easily found via an Internet search. Do you know which atom is the anion (i.e., how an anion is defined)?
 

What is a unit cell?

A unit cell is the smallest repeating unit of a crystal lattice in a solid. It is a three-dimensional structure that can be used to represent the entire crystal.

Why is the unit cell important in crystallography?

The unit cell is important because it allows us to describe and understand the underlying structure and properties of a crystal. By studying the unit cell, we can determine the arrangement of atoms and molecules within a crystal and how they interact with each other.

How is the unit cell determined experimentally?

The unit cell can be determined experimentally through techniques such as X-ray crystallography or electron diffraction. These methods involve analyzing the diffraction patterns produced by a crystal, which can then be used to determine the size and shape of the unit cell.

What are the different types of unit cells?

There are seven types of unit cells: cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, monoclinic, and triclinic. These types differ in the angles and lengths of their sides, which affects the overall symmetry of the crystal.

How is the unit cell related to the crystal lattice?

The unit cell is the basic building block of the crystal lattice. The lattice is made up of multiple unit cells stacked together in a repeating pattern. The size and shape of the unit cell determine the overall symmetry and properties of the crystal lattice.

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