Physical Chemistry: Partial Molar Volumes NaCl Solutions

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SUMMARY

The discussion focuses on the concept of partial molar volumes in NaCl solutions, specifically addressing how the total volume of a mixture is not simply the sum of the individual volumes. The equation V = n1V1 + n2V2 is highlighted, where V represents the total volume, n1 and n2 are the moles of each component, and V1 and V2 are the partial molar volumes. The participants also mention conducting experiments with alcohols and water, noting that while the principle remains consistent, the behavior may differ for salts like NaCl.

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tam
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I'm actually taking a physical chem course and i have to hand in a report onpartial molar volumes in NaCl solutions...I'm not really sure how the concept works and I'm wondering if anyone could clarify! Thanks
 
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Heh, just did this lab, so let's see if I can help.

The idea with partial molar volumes is that when you mix a certain volume of some substance with a certain volume of another, the total volume in many cases is not simply V(A) + V(B). The total volume can be represented by the equation [tex]V~=~n_1\overline{V_1}~+~n_2\overline{ V_2}[/tex], where V is the total volume, n1 and n2 are the quantities of the mixture in moles, and V1 and V2 are defined as the partial molar volumes of the components of the mixture.

We mixed alcohols and water, and its a little different for salts, though I suppose the principle is basically the same.
 
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