Exothermic Reaction Origin: What is the Source?

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    Exothermic Origin
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Discussion Overview

The discussion revolves around the origin of the energy liberated during exothermic reactions, exploring the underlying principles and examples of such reactions. Participants examine the concepts of bond formation and breaking, as well as specific instances in chemical and biological systems.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant inquires about the source of energy released in exothermic reactions, expressing a need for clarity.
  • Another participant suggests that the energy originates from potential energy stored in molecular bonds, using a mouse trap as an analogy.
  • It is noted that bond making is an exothermic process, particularly when more bonds are formed than broken, and that strong bonds formed from weak bonds also result in energy release.
  • An example is provided involving sulfuric acid dissolving in water, where the process is described as releasing energy due to the formation of more stable bonds in the aqueous state compared to the non-aqueous state.
  • In biological systems, the cleavage of phosphorus-oxygen bonds in ATP is mentioned as a source of significant energy release, framing ATP as an "energy bank".

Areas of Agreement / Disagreement

Participants present various perspectives on the origin of energy in exothermic reactions, with no consensus reached on a singular explanation. Different examples and analogies are offered, indicating a range of interpretations.

Contextual Notes

Some assumptions about bond stability and energy flow are implied but not explicitly stated. The discussion does not resolve the complexities of energy transformations in chemical reactions.

Farside
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what is the origin of the engery liberated in an exothermic reaction? I've been hitting the books for this but can't find it. Seems simple enough though. I just need to be sure.
 
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Its a form of potential energy that is stored in the bonds of a molecule.. Think of a mouse trap.
 
Bond making is an exothermic reaction (opposite of bond breaking in which energy must be applied to break the bonds). If there is a reaction in which more bonds are made than bonds broken than it is an exothermic reaction. The reaction in which weak bonds are broken and strong bonds are formed is also an exothermic reaction.
Hope this helps.
Ab S.
 
I'll give an example, maybe this will clarify something.

Sulfuric acid dissolves in water with evolution of great amounts of heat. In here, as DeathKnight and so-crates said, some bonds are broken and their energies are evolved as unused energy. This can be explained in another point of view, sulfuric acid dissolved in water has a lower energy, thus more stable than its non-aqueous counterpart. This results with an energy flow outside, what we call as "exothermic" reaction.

In biological sytems, phosphorus-oxygen bond cleavages, as in ATP and ADP, etc., are used frequently, since it gives great energy gain. Adenosine triphosphate can be regarded as an "energy bank", which releases energy upon "application".
 

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