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Ionic or covalent in tetrahydroxoaluminate ion? |
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| Feb19-12, 10:04 AM | #1 |
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Ionic or covalent in tetrahydroxoaluminate ion?
Consider the metal-ligand complex of the tetrahydroxoaluminate ion. [tex][Al(OH)_{4}]^-[/tex]
In this ion, the aluminium is bonded with four hydroxides where each hydroxide is a ligand. My question: Is the aluminium-hydroxide bond ionic or covalent? I can think of the ionic one working in someway like this: [tex]Al^{+3} + 4(OH)^- \rightarrow [Al(OH)_{4}]^- [/tex] I can also think of it as being covalent: [tex]Al + 3(OH) + (OH)^- \rightarrow [Al(OH)_{4}]^- [/tex] Which would be more "correct"? Aluminium is a metal, so you would expect it to form ionic bonds right? But I heard of instances where metals form covalent bonds, especially in metal complexes. So I hope I can clear this confusion in my head somehow. Also, will a complete octet be formed in both cases? Thanks! BiP |
| Feb19-12, 12:42 PM | #2 |
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I would go for covalent bonding it seems more appropriate, Hydroxide ions do posses a lone pair of electrons. Hence they can provide both the electrons to form a dative covalent bond.
Metal complexes do commonly form covalent bonds, especially transition metals. the metal complex will form a tetrahedral structure in this case hydroxide ions act as ligands... http://www.see.murdoch.edu.au/info/s...equations.html click on the link and look for equations 27-29 |
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