Hello Peter Donis, thank you for your response. I did start trying to play with double and half angle trig identities, but you are right that I did not factor ##\frac{1}{\cos{\theta}}## first. When I do, I get:
$$(\cos({\theta}) -1)a - (\sin({\theta})\exp{-i\phi})b = 0$$
From there, I have tried...