Recent content by khanhhung2512

  1. K

    Can He2 Molecules Form and Why Do They Dissociate?

    I still haven't understood all of what you're saying, but it's making sense to me now. Thank you very much. One more question, please. What kind of book do I need to read or study to have such a good knowledge of physical chemistry as yours, or at least to be able to fully comprehend this He2...
  2. K

    Can He2 Molecules Form and Why Do They Dissociate?

    I mean, what's the reason the stable, low-energy excited state would spontaneously drop electron to transform to the unstable, high-energy ground state?
  3. K

    Can He2 Molecules Form and Why Do They Dissociate?

    Suppose you're correct, then why would stabler excited He2 molecules spontaneously break apart as the electron(s) fall back to the ground state?
  4. K

    Can He2 Molecules Form and Why Do They Dissociate?

    Because the ground state is lower in energy, and thus is stabler than the excited state, whatever bond orders they have. My explanation for this He2 question is as followed: In high-energy environments, some He atoms will exist in the excited state. Two He atoms might then form a He2 molecule...
  5. K

    Can He2 Molecules Form and Why Do They Dissociate?

    I think the question didn't tell us anything about the configuration of the He2 molecule in high-energy environment.
  6. K

    Can He2 Molecules Form and Why Do They Dissociate?

    Because with this explanation, excited-state configuration (σ1s)2(σ1s*)1(σ2s)1 with bond order 1 seems stabler than ground-state configuration (σ1s)2(σ1s*)2 with bond order 0, while it's not the case.
  7. K

    Can He2 Molecules Form and Why Do They Dissociate?

    This is a question in "Chemical Principles, 6th Edition, Steven Zumdahl": Bond energy has been defined in the text as the amount of energy required to break a chemical bond, so we have come to think of the addition of energy as breaking bonds. However, in some cases the addition of energy can...
  8. K

    Ligand field theory and CuCl2 colors

    These are two answers I found on the net http://answers.yahoo.com/question/index?qid=20110915202418AA2v9AN While both answers seem wrong to me, one mentioned Advanced Inorganic Chemistry 6th ed (1999). p 868-869 (F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann). If anyone has access to...
  9. K

    Ligand field theory and CuCl2 colors

    Well, the color we see is complementary to the color absorbed.
  10. K

    Ligand field theory and CuCl2 colors

    Copper (ii) chloride is a light brown solid, which slowly absorbs moisture to form a blue-green dihydrate. According to ligand field theory, water is a stronger field ligand than chloride. As a result, the dihydrate form should have a larger d orbital splitting than the anhydrous form. Thus...
  11. K

    Rotation of CO2 bonds and triple bonds.

    Thanks. There's still one part in my questions. Is triple bond cylindrically symmetric?
  12. K

    Rotation of CO2 bonds and triple bonds.

    I read in several websites that triple bonds cannot rotate freely. However, I've also read in the book "Chemical Principles" the following lines: "Various types of evidence suggest that the electron density around the two C-O bonds in CO2 is actually cylindrically symmetric—that is, the...
  13. K

    Graduate Radiation in photoelectric effect.

    Yes, that's what I think. However, textbooks don't seem to incorporate that radiation in photoelectric effect. Is it because that amount of energy (according to Larmor formula) is too small and negligible?
  14. K

    Graduate Radiation in photoelectric effect.

    Textbooks say that by measuring the stopping potential V0, we can determine the maximum kinetic energy with which electrons leave the cathode: eV0 = Kmax However, as I know, when we apply the stopping potential, the electrons will decelerate and radiate parts of their energies. Thus, the...