Will liquid gallium wet oxygen-free molybdenum in a vacuum?

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SUMMARY

Liquid gallium wets oxygen-free molybdenum in a vacuum, leading to the formation of an ordered Mo3Ga alloy with a β-W crystal structure when heated above 600 °C. Field ion microscopy studies by Nishikawa and Utsumi (J. Appl. Phys. 44, 955–964, 1973) confirm the absence of pseudomorphic gallium layers and reveal anisotropic binding forces affecting molybdenum surface atom stability on various crystal planes. The interaction results in distinct structural and stability variations on the (001), (130), (120), and (110) planes of the alloy. These findings establish that gallium-molybdenum alloying occurs under vacuum conditions at elevated temperatures.

PREREQUISITES

  • Field Ion Microscopy (FIM) techniques
  • Crystallography of β-W (beta-tungsten) structure
  • Metal alloy phase formation and thermodynamics above 600 °C
  • Surface science of molybdenum and gallium interactions in vacuum

NEXT STEPS

  • Study Mo3Ga alloy phase diagrams and stability ranges
  • Explore anisotropic binding forces in β-W structured alloys
  • Investigate surface atom stability variations on molybdenum crystal planes
  • Apply Field Ion Microscopy to analyze metal-metal interactions in vacuum

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Materials scientists, surface physicists, vacuum technology researchers, and metallurgists investigating metal wetting, alloy formation, and surface interactions under vacuum conditions.

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liquid gallium wet oxygen-free molybdenum
Hi everyone, In a vacuum, will liquid gallium wet the surface of oxygen-free molybdenum upon contact?
 
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Maybe, this abstract gives an indication:

Gallium was deposited on a molybdenum tip by making contact between the tip and liquid gallium in vacuum. Pseudomorphic gallium could not be observed clearly. The product of the Mo–Ga reaction above 600 °C was found to be the ordered alloy, Mo3Ga, with the β‐W structure and no other structure was observed. The difference between the crystal structure and the observed image of the (001), (130), (120), and (110) planes of the alloy are explained by the unobservability of the gallium atom and by the variation of the stability of the molybdenum surface atoms. The observed differences in the stability of the surface atoms on these planes are interpreted in terms of anisotropic binding forces in the β‐W structure of the alloy.

From „Field ion microscope study on the interaction of gallium with metals. II. Alloy formation with molybdenum and anisotropic binding force in Mo3Ga” by O Nishikawa, T Utsumi, J. Appl. Phys. 44, 955–964 (1973)
 
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Lord Jestocost said:
Maybe, this abstract gives an indication:

Gallium was deposited on a molybdenum tip by making contact between the tip and liquid gallium in vacuum. Pseudomorphic gallium could not be observed clearly. The product of the Mo–Ga reaction above 600 °C was found to be the ordered alloy, Mo3Ga, with the β‐W structure and no other structure was observed. The difference between the crystal structure and the observed image of the (001), (130), (120), and (110) planes of the alloy are explained by the unobservability of the gallium atom and by the variation of the stability of the molybdenum surface atoms. The observed differences in the stability of the surface atoms on these planes are interpreted in terms of anisotropic binding forces in the β‐W structure of the alloy.

From „Field ion microscope study on the interaction of gallium with metals. II. Alloy formation with molybdenum and anisotropic binding force in Mo3Ga” by O Nishikawa, T Utsumi, J. Appl. Phys. 44, 955–964 (1973)
Thanks for your reply.
 
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