Quantum mechanics probability

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Discussion Overview

The discussion revolves around the definition of probability density in quantum mechanics, specifically why it is represented as ##|\psi|^2## rather than just ##|\psi|##. Participants explore theoretical implications, mathematical formulations, and interpretations related to quantum mechanics and the Born rule.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • Some participants question why probability density is defined as ##|\psi|^2##, suggesting that ##|\psi|## is also a positive quantity.
  • Others argue that since ##\psi## is a complex number, taking the modulus alone does not yield the correct statistics.
  • One participant notes that Born's rule is a fundamental postulate of quantum theory that has not been derived from more fundamental principles.
  • Another participant references historical context, mentioning Einstein's influence on the interpretation of wave functions as probability densities.
  • Some participants highlight that the normalization condition of ##|\psi|^2## leads to a total probability of 1, which is essential for physical interpretation.
  • There is discussion about the continuity equation involving probability density and current, with some participants asserting that this framework is not exclusive to Bohm's interpretation.
  • One participant raises a question about the definition of the current and its relation to conservation laws, indicating that it is derived using Noether's theorem.
  • Another participant introduces a mathematical transformation involving the Gauss theorem to discuss normalization and its implications for physical interpretation.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation and implications of using ##|\psi|^2## as probability density. While some agree on certain mathematical properties and the necessity of normalization, there is no consensus on the foundational reasons behind these definitions or their physical meanings.

Contextual Notes

Participants mention limitations related to the normalization of wave functions and the implications of using different function spaces (L^2 vs. L^1). There are unresolved questions about the physical meaning of certain mathematical constructs introduced in the discussion.

Who May Find This Useful

This discussion may be of interest to those studying quantum mechanics, particularly in understanding the foundational aspects of probability density, wave functions, and the implications of various interpretations in quantum theory.

matematikuvol
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In the one moment you accept something in the other you're not sure why? Why probability density in quantum mechanics is defined as ##|\psi|^2## and no just ##|\psi|## if we know that ##|\psi|## is also positive quantity.
 
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matematikuvol said:
In the one moment you accept something in the other you're not sure why? Why probability density in quantum mechanics is defined as ##|\psi|^2## and no just ##|\psi|## if we know that ##|\psi|## is also positive quantity.
Because - in general, ##\psi## is a complex number ... go look at how complex numbers work. i.e., ##|\psi(\vec{r},t)|## is not, in general, positive everywhere.
Consider a particle in a 1D unit box, prepared in the n=2 state.

Mainly the model is the way it is because that is what nature does.
Just taking the modulus does not give the correct statistics.
 
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Of course |\psi(t,\vec{x})| is a positive semidefinite real expression everywhere, since the modulus of a complex number is a positive real number (or 0 if the number itself is 0).

Born's rule is, as far as we know, one of the fundamental postulates of quantum theory. It has not yet been deduced from other more fundamental postulates yet. So we cannot explain, why this interpretation of the wave function works to describe nature.

Recently, however it has been tested experimentally that it holds with very high accuracy:

http://physicsworld.com/cws/article/news/2010/jul/22/quantum-theory-survives-its-latest-ordeal
 
I believed that theory is consistent. But why Bohm took ##|\psi(x,t)|^2##? Is there some bond with
\vec{j}=\frac{\hbar}{2im}(\psi^*\frac{d}{dx}\psi-\psi\frac{d}{dx}\psi^*)
 
A Google search for "Born rule" led me to the Wikipedia page

http://en.wikipedia.org/wiki/Born_rule

which refers to Born's 1954 Nobel Prize lecture

http://nobelprize.org/physics/laureates/1954/born-lecture.pdf

in which he talks about the origin of his famous rule.

Max Born said:
Again an idea of Einstein’s gave me the lead. He had tried to make the duality of particles - light quanta or photons - and waves comprehensible by interpreting the square of the optical wave amplitudes as probability density for the occurrence of photons. This concept could at once be carried over to the psi-function: |psi|2 ought to represent the probability density for electrons (or other particles)

Classically, the square of the electric field (or of the magnetic field) is proportional to the energy density carried by the field, and therefore also to the number-density of photons (photons per m3)in the field. For a weak field (small number of photons), we have to talk about probability rather than number-density.
 
First indication to use |\psi(x,t)|^2 is that this quantity is normalised such that the integral is = 1 which means that the probability to find the particle anywhere is 100%.

The second indication is that the density

\rho = |\psi|^2

plus the current

\vec{j}=\frac{\hbar}{2im}(\psi^*\nabla\psi-\psi\nabla\psi^*)

fulfill a continuity equation

\frac{\partial}{\partial t}\rho + \nabla \vec{j} = 0

which means that the probability is conserved. This follows in a rather general way using the Lagrangian corresponding to the Schrödinger equation plus Noether's theorem. It is not special for Bohm's interpretation.

All this works for |\psi(x,t)|^2 not for |\psi(x,t)|
 
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tom.stoer said:
First indication to use |\psi(x,t)|^2 is that this quantity is normalised such that the integral is = 1 which means that the probability to find the particle anywhere is 100%.

Well I agree with second reason. But you can normalized state in such way that
\int^{\infty}_{-\infty}|\psi(x,t)|dx=1
Right?
And the second one. Why current is defined like
\vec{j}=\frac{\hbar}{2im}(\psi^*\frac{d}{dx}\psi-\psi\frac{d}{dx}\psi^*)
 
matematikuvol said:
Well I agree with second reason. But you can normalized state in such way that
\int^{\infty}_{-\infty}|\psi(x,t)|dx=1
Right?
No, because we are using the space L^2(R^3) for the space of wavefunctions. Not every L^2 function is also a L^1 function. We can't use L^1, because it's not a Hilbert space.

And the second one. Why current is defined like
\vec{j}=\frac{\hbar}{2im}(\psi^*\frac{d}{dx}\psi-\psi\frac{d}{dx}\psi^*)
Because this definition turns out to give you a conserved current.
 
rubi said:
No, because we are using the space L^2(R^3) for the space of wavefunctions. Not every L^2 function is also a L^1 function. We can't use L^1, because it's not a Hilbert space.
Correct; L^2 is the only Lp-Banach-Space which is also a Hilbert space.

rubi said:
Because this definition turns out to give you a conserved current.
Using Noether's theorem this current can be derived.

matematikuvol said:
But you can normalized state in such way that
\int^{\infty}_{-\infty}|\psi(x,t)|dx=1
Right?
No.

You can normalize the density for one time t, but time evolution (Schrödinger equation) will not respect this normalization, i.e. it will be violated for t' > t.

As I said
tom.stoer said:
all this works for |\psi(x,t)|^2 not for |\psi(x,t)|
 
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  • #10
tom.stoer said:
Using Noether's theorem this current can be derived

Yeah, given Schrödinger's equation alone, with no assumption about the meaning of \vert \Psi \vert^2, you can prove that the latter is a conserved quantity (when integrated over all space). So it's pretty natural to interpret it as something conserved: probability, or charge, or energy...
 
  • #11
stevendaryl said:
Yeah, given Schrödinger's equation alone, with no assumption about the meaning of \vert \Psi \vert^2, you can prove that the latter is a conserved quantity ...
Yes, you can prove that, but you cannot derive it w/o Noether's theorem; you have to guess it.
 
  • #12
Hello, I have a question concerning normalization. I start from integral |psi|^2 dV = 1, which means somehow that the particle should be in the universe with probability 1. Now using the the Gauss theorem in such a way that if we have a vector function

Fi: div Fi = |psi|^2,
integral |psi|^2 dV = integral div Fi dv =(Gauss) integral Fi dA = 1 so the normalization is transformed from volumetric to surface integral.

The unit of psi is [psi]=1/m^(3/2) so [psi^2]=1/m^3 and vector [Fi] = 1/m^2.

So we prepared a "surface probability density vector" from the scalar volumetric probability density |psi|^2.

I would like to know whether this trick with mathematics could have some physical meaning at all? It looks like that the internal probability appeared on the surface of the universe somehow, also I am aware that probability vector sounds quite unphysical.

Thank you for your answer.
 

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