Angular momentum ladder operators and state transitions

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SUMMARY

The discussion centers on the significance of ladder operators in quantum mechanics, specifically their eigenvalues and their role in magnetic transitions. It is established that ladder operators, which are not self-adjoint, do not possess meaningful eigenvalues. However, the intensity of transitions between quantum states, particularly in NMR spectroscopy, is related to these operators, as highlighted by Stanislav Sykora's work with Mnova software. The relationship between the matrix elements of the spin-raising operator and the intensity of transitions is confirmed, although the eigenvalues of the ladder operators remain insignificant.

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  • Understanding of quantum mechanics concepts, particularly spin and state vectors.
  • Familiarity with ladder operators and their mathematical properties.
  • Knowledge of Hermitian operators and their significance in quantum mechanics.
  • Basic principles of NMR spectroscopy and its relation to quantum transitions.
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  • Research the properties of Hermitian operators in quantum mechanics.
  • Explore the mathematical formulation of ladder operators and their applications.
  • Study the relationship between magnetic moments and Larmor frequency in NMR.
  • Investigate the role of matrix elements in quantum state transitions.
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Quantum physicists, students of quantum mechanics, NMR spectroscopy researchers, and anyone interested in the mathematical foundations of quantum state transitions.

JeremyEbert
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What is the significance of the ladder operators eigenvalues as they act on the different magnetic quantum numbers, ml and ms to raise or lower their values?
How do their eigenvalues relate to the actual magnetic transitions from one state to the next?
 
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Since the 'ladder operators' are not (essentially) self-adjoint, there's no significance of their eigenvalues whatsoever.
 
dextercioby said:
Since the 'ladder operators' are not (essentially) self-adjoint, there's no significance of their eigenvalues whatsoever.

Thanks dextercioby. Being very new to the concepts of Hermitian operators, I am obviously having a hard time grasping this explanation but I will continue to research the subject.

My question stems from something I read on OEIS related to NMR spectroscopy. Stanislav Sykora, among other things, maintains a dll for Mnova software. It is used for NMR functionality. On http://oeis.org/A003991, he comments on the intensity of the transition between the states of spin being related to these ladder operators. Is his statement incorrect? If correct, doesn't this give significance to their eigenvalues?

"Consider a particle with spin S (a half-integer) and 2S+1 quantum states |m>, m = -S,-S+1,...,S-1,S.
Then the matrix element <m+1|S_+|m> = sqrt((S+m+1)(S-m)) of the spin-raising operator is the
square-root of the triangular (tabl) element T(r,o) of this sequence in row r = 2S, and at offset o=2(S+m).
T(r,o) is also the intensity |<m+1|S_+|m><m|S_-|m+1>| of the transition between the states |m> and |m+1>.
For example, the five transitions between the 6 states of a spin S=5/2 particle have relative intensities 5,8,9,8,5.
The total intensity of all spin 5/2 transitions (relative to spin 1/2) is 35, which is the tetrahedral number A000292(5).
[Stanislav Sykora, May 26 2012]"
 
That is correct, but the eigenvalues still mean nothing. The state vectors (kets) are not theirs, but pertain to the spin components (S_z most common).
 
dextercioby said:
That is correct, but the eigenvalues still mean nothing. The state vectors (kets) are not theirs, but pertain to the spin components (S_z most common).

Ah, I've heard them described as "in between the state vectors", this makes sense. Is the intensity of the transition between the states referring to the intensity of the magnetic moment? Does this have something to do with the Larmor frequency?

Thanks again for your responses.
 
JeremyEbert said:
Ah, I've heard them described as "in between the state vectors", this makes sense. Is the intensity of the transition between the states referring to the intensity of the magnetic moment? Does this have something to do with the Larmor frequency?

Thanks again for your responses.

I guess my question comes down to;
Can I visualize the ladder operator values as vector rejection values?

http://en.wikipedia.org/wiki/Vector_projection#Vector_rejection_3
 
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