Calculating Heat Released in Ba(s) + O2(g) → 2BaO(s) Reaction

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Discussion Overview

The discussion centers on calculating the heat released during the reaction of barium with oxygen to form barium oxide. Participants explore the relationship between the stoichiometry of the reaction and the enthalpy change, particularly in the context of a homework problem.

Discussion Character

  • Homework-related, Technical explanation

Main Points Raised

  • One participant calculates the moles of Ba and attempts to determine the heat released based on the given enthalpy change of -1107 kJ for the reaction.
  • Another participant clarifies that the enthalpy value applies to the reaction as a whole, indicating that it corresponds to the consumption of 2 moles of Ba or 1 mole of O2.
  • A subsequent participant questions the necessity of considering the coefficient of oxygen when barium is the limiting reactant.
  • Another participant notes that the enthalpy value is given per 'mole of reaction', which may not always align with the moles of a specific reactant.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation of the enthalpy change in relation to the limiting reactant and the coefficients in the balanced equation. The discussion remains unresolved regarding the correct approach to the calculation.

Contextual Notes

There are limitations in the assumptions made about the limiting reactant and the application of the enthalpy change to specific reactants versus the overall reaction.

geffman1
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The value of H° for the reaction below is -1107 kJ:
2Ba(s) + O2(g) --> 2BaO(s)

How many kJ of heat are released when 5.75 g of Ba(s) reacts completely with oxygen fo form BaO(s)?


i worked out the moles of Ba which was 0.0412 then times by -1107 whcih is 46.4 however the answer is 23.2, i don't understand why becasue the is a 2 to 2 relationship between Ba and BaO? any help would be good




Homework Equations





The Attempt at a Solution

 
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The specific enthalpy of reaction would be -1107 kJ per 2 moles of Ba consumed (or per mole of oxygen consumed or per 2 moles of BaO produced). This would give the 23.2 kJ of heat released.
 
thanks, but how do u no you have to use the coeffecient of the oxygen, when the Ba is limiting?
 
Value is given not per mole of Ba, but per so called 'mole of reaction'.

That's not always the case.
 

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