The matrix elements depend on the order of the basis vectors, so you need to choose a way to order them, e.g. (|00>,|01>,|10>,|11>). The matrix of |11><11| with respect to this ordered basis is
\begin{pmatrix}0 & 0 & 0 & 0\\ 0 & 0 & 0 & 0\\ 0 & 0 & 0 & 0\\ 0 & 0 & 0 & 1 \end{pmatrix} This could be anticipated from the fact that |11><11| is a projection operator for a 1-dimensional subspace of the vector space, which is 4-dimensional.
The matrix of any operator T with respect to this ordered basis is
\begin{pmatrix}\langle 00|T|00\rangle & \langle 00|T|01\rangle &\dots & &\\ \langle 01|T|00\rangle & \langle 01|T|01\rangle & \dots \\ \vdots & \vdots & \ddots \\ \end{pmatrix}
For more information, see the https://www.physicsforums.com/showthread.php?t=694922 about the relationship between linear operators and matrices.