Calculating the Formula of a Hydrated Compound

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To calculate the value of x in the hydrated compound Na2CO3.xH2O, the moles of HCl used in the titration were found to be 0.00245, leading to 0.001225 moles of Na2CO3 based on the 1:2 molar ratio. This was scaled up to the total solution volume, resulting in 0.01225 moles of Na2CO3 in 250 cm3. The calculated molar mass of Na2CO3.xH2O was approximated at 286 g/mol, while the known molar mass of anhydrous Na2CO3 is 106 g/mol. The difference in molar mass indicates the contribution of water molecules, allowing for the determination of x. The method used for calculation was generally correct, but clarification on the significance of the molar mass difference was requested.
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Homework Statement



Sodium carbonate exists in hydrated form, Na2CO3.xH2O, in the solid state. 3.5 g of a sodium carbonate sample was dissolved in water and the volume made up to 250 cm3. 25.0 cm3 of this solution was titrated against 0.1 moldm-3 HCl and 24.5 cm3 of the acid were required. Calculate the value of x given the equation:

Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O

Homework Equations



NO. of Moles = Conc. x volume/1000

The Attempt at a Solution


I have attempted this question in this way,
Moles of HCI = 0.1 x 24.5 / 1000 = 0.00245
Then looking at the molar ratio, I see 1:2 ratio of Sodium carbonate and HCI.
So, Moles of Na2CO3, is 0.00245/2 = 0.001225 moles in 25 cm3
Then I did the NO. of moles for Na2CO3 in 250cm3 so 250cm3/25cm3 = 10 which is the multiplier, then i did 10 x 0.001225 = 0.01225 mol
I did the Molar Mass of Na2CO3 which is 3.5/0.01225 = 285.7142.. which rounds to 286.
I assumed the Mr of Na2CO3.xH2O is 286, as the mark scheme assumed that
I don't know what to do after this, can someone please help me, as this is Homework!
Thank you!
 
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Many ways to skin that cat, but if you got to the molar mass... What is the molar mass of anhydrous Na2CO3? Why is your number larger? By how much? What does the difference man?
 
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Borek said:
Many ways to skin that cat, but if you got to the molar mass... What is the molar mass of anhydrous Na2CO3? Why is your number larger? By how much? What does the difference man?
The molar mass of Na2CO3 is 106..
Is my method right, or have I done it differently/wrong?
 
Try to answer my other questions. You did everything OK so far.
 
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