Can iron react with other inorganic substances and form a red precipitate?

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    Iron Reactions
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Discussion Overview

The discussion revolves around the potential reactions of iron with various inorganic substances, specifically focusing on the formation of red precipitates. Participants explore different chemical combinations involving iron(III) thiocyanate and other reagents, considering both theoretical and practical aspects of these reactions.

Discussion Character

  • Exploratory
  • Chemical reasoning
  • Debate/contested

Main Points Raised

  • One participant, Paulo, questions whether mixing KNO3 with Fe(SCN)3 and Na2SO4 could yield a red precipitate of FeSO4 along with NaNO3 and KSCN.
  • Another participant claims that a reaction does occur, suggesting a balanced equation involving KNO3, Fe(SCN)3, and Na2SO4 leading to the formation of Fe2(SO4)3 as a red precipitate.
  • A participant proposes the addition of NaOH as a potential method to precipitate iron compounds, although this is not universally accepted.
  • Another participant argues against the use of NaOH for precipitating KSCN, noting its solubility issues and cost considerations.

Areas of Agreement / Disagreement

Participants express differing views on the effectiveness of NaOH in precipitating KSCN and the specific outcomes of the proposed reactions, indicating that the discussion remains unresolved with multiple competing perspectives.

Contextual Notes

Some assumptions about solubility and reaction conditions are not fully explored, and there are unresolved questions regarding the specific mechanisms of precipitation and the feasibility of the proposed reactions.

alotropia_entropia
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I'm with a small doubt let me show for you:

I have a solution:
KNO3 + Fe(SCN)3

Plus:
Na2SO4 (aq)

I would like to know if could happen it?

---> NaNO3 + FeSO4↓ppt red + KSCN

Or plus:

NaOH (aq)

Could Happen ?
----> NaNO3+ Fe(OH)3 ↓ppt red +KSCN

Thank you

Paulo
 
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Yes, it happened : But
6KNO3+ 2Fe(SCN)3+ 3Na2SO4---->Fe2(SO4)3 ↓ppt red + 6KSCN (aq) + 6 NaNO3 (aq)

Now I want to know how precipitate the [SCN] from aqueous solution NaNO3 + KSCN

Could anyone help me?
Thanks
 
Maybe it could being done add NaOH (aq)?
 
NaOH isn't good to precipitate KSCN ... the KSCN is unsoluble into etanol but is a bit expansive...until now
 

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