Commutation relations of P and H

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    Commutation Relations
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The discussion centers on the commutation relations between the momentum operator (P) and the Hamiltonian operator (H) in quantum mechanics, specifically within the context of an infinite square well. It is established that the commutator [P, H] can be calculated, yielding the result [P, H] = -dV/dx, where V(x) represents the potential energy. The discussion emphasizes that the domain of the product operator must intersect with the domain of the Hamiltonian, specifically D(AH) ∩ D(HA) ≠ ∅, which is crucial for the validity of the commutation relations.

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Can we always calculate the commutation relations of two observables? If so, what’s the commutator of P (momentum) and H (Hamiltonian) in infinite square well, considering that the momentum is not a conserved quantity?
 
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For a quantum observable, call it A, it's not important that it doesn;t commute with the Hamiltonian. It only matters that

D(AH)∩D(HA)≠\emptyset

and the domain of the product operator is the subset of D(H), such as

I(H)⊂D(A)
 
Remember that [P,.] works like a derivative for x. So, generically, for H = P^2/2m + V(x) where V is any potential, [P,H] = -dV/dx. In classical mechanics, this is the force. For infinite square potential, it gives two delta spikes at the edges of the box.
 

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