Composition of a Mixture by Acid-Base Titration

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Discussion Overview

The discussion revolves around a chemistry problem involving the composition of a solid mixture of table salt and citric acid, specifically focusing on how to calculate the mass percent of citric acid in the mixture using acid-base titration data.

Discussion Character

  • Homework-related
  • Mathematical reasoning

Main Points Raised

  • One participant requests help with solving a titration problem involving a mixture of NaCl and citric acid.
  • Another participant suggests starting by writing out the neutralization equation for the titration.
  • A participant expresses uncertainty about solving for M2 in the equation M1 x V1 = M2 x V2.
  • One participant advises calculating the moles of NaOH used, noting that at the endpoint, the amount of OH^{-} is equivalent to the amount of H^{+} in the titration mixture.
  • A later reply questions which endpoint is being referred to in the context of the titration, suggesting that the third endpoint may be relevant.
  • Another participant agrees that the third endpoint is likely the one being referenced.

Areas of Agreement / Disagreement

Participants express differing levels of understanding and approaches to the problem, with some agreeing on the need to clarify the endpoint of the titration while others focus on the mathematical aspects. No consensus is reached on the specific method to solve the problem.

Contextual Notes

There is ambiguity regarding the endpoint of the titration, as well as the specific course level of the participants, which may influence the approach to solving the problem.

veena
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A 1.00-g solid sample containing a mixture of table salt (NaCl) and citric acid (H3C6H5O7, a triprotic acid) is dissolved in 15 mL of water.
Titration of the acid solution requires 40.00 mL of 0.2003 M NaOH solution to reach the endpoint.
Calculate the mass percent H3C6H5O7 in the solid mixture.


Can someone please explain how to do this problem...??
 
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Start by writing out the neutralization equation.
 
I have tried but i don't know how to solve for M2

M1 x V1 = M2 x V2

can u help please
 
Start by writing out the neutralization equation.
 
First, figure out how many moles of NaOH were used, this will be equivalent to the amount of OH^{-} in the titration mixture, if its the end point OH^{-} = H^{+}, I hope that gets you closer to your final goal, as its bad policy for us to just give you a full answer.

Or, just do what chem said, write the neutralization equation (I do the more manual way personally ¬_¬ )
 
veena said:
A 1.00-g solid sample containing a mixture of table salt (NaCl) and citric acid (H3C6H5O7, a triprotic acid) is dissolved in 15 mL of water.
Titration of the acid solution requires 40.00 mL of 0.2003 M NaOH solution to reach the endpoint.
Calculate the mass percent H3C6H5O7 in the solid mixture.


Can someone please explain how to do this problem...??
"triprotic acid"... Which endpoint? Is your course "elementary chemistry" or is it undergraduate "Quantitative Chemistry"?
 
I think he will be referring to the third endpoint, rather than the first.
 

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