Derivation of Spin-orbit Coupling

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SUMMARY

The discussion focuses on the derivation of spin-orbit coupling as presented in Griffiths's quantum mechanics textbook. Key equations include the magnetic dipole moment, \vec{\mu}=\frac{e\pi r^2}{T}\hat{n}, and the angular momentum, \vec{S}=\frac{2m\pi r^2}{T}\hat{n}, leading to the relation \vec{\mu}=\frac{e}{2m}\vec{S}. The Hamiltonian is expressed as H=-\frac{1}{4\pi\epsilon_0}\frac{e^2}{m^2c^2r^3}\vec{L}\cdot\vec{S}. The discussion highlights the necessity of considering Thomas's precession in non-inertial frames, which introduces a factor of 1/2 in the calculations.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly spin and angular momentum.
  • Familiarity with classical electromagnetism, specifically magnetic dipole moments.
  • Knowledge of the Dirac Equation and its implications in quantum mechanics.
  • Basic grasp of non-inertial reference frames and their effects on physical systems.
NEXT STEPS
  • Study the derivation of spin-orbit coupling using the Dirac Equation.
  • Research Thomas's precession and its role in quantum mechanics.
  • Examine Griffiths's quantum mechanics textbook, particularly Chapter 6 on spin-orbit coupling.
  • Explore the implications of non-inertial frames in quantum mechanics through additional literature.
USEFUL FOR

Students and professionals in physics, particularly those focused on quantum mechanics, theoretical physicists, and educators seeking to deepen their understanding of spin-orbit coupling and related concepts.

kiwakwok
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I was reading Griffiths's book on quantum mechanics.

In chapter 6, he tried to derive the spin-orbit coupling using a classical approach.
H=-\vec{\mu}\cdot \vec{B}

1. Finding the relation between \vec{μ} and \vec{S}
He consider a spinning charged ring with mass m, radius r, total charge e and period T.
Magnetic Dipole Moment: \vec{\mu}=i\vec{A}=\frac{e\pi r^2}{T}\hat{n}
(Spin) Angular Momentum: \vec{S}=\tilde{I}\vec{\omega}=\frac{2m\pi r^2}{T}\hat{n}
\vec{\mu}=\frac{e}{2m}\vec{S}
Dirac: \frac{e}{2m}\rightarrow\frac{e}{m}

2. Find the magnetic field \vec{b}
He consider the rest frame of electron.
\vec{B}=\frac{\mu_0 i}{2r}\hat{n}=\frac{1}{c^2\epsilon_0}\frac{e/T}{2r}\hat{n}=\frac{1}{4\pi\epsilon_0}\frac{e}{mc^2r^3}\vec{L}

3. Combining both terms
H=-\frac{1}{4\pi\epsilon_0}\frac{e^2}{m^2c^2r^3}\vec{L}\cdot\vec{S}

Then he point out that when we choose the electron's rest frame, there is one problem as it is a non-inertial frame. Therefore, we need to consider the Thomas's precession, which gives a factor of 1/2. Finally, it cancels with the 2 we multiplied to the classically derived gyromagnetic ratio.


My problem is when we choose an accelerating frame, obviously we need some modifications. But, how should we modify? and how can we get the factor of 1/2 from Thomas's precession?

Thanks in advance.
 
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kiwakwok, Unfortunately, almost all quantum books slide over the spin-orbit issue with this approach, in which quantum mechanics is temporarily abandoned, the electron is imagined to travel in a definite orbit about the nucleus, and the interaction is treated in a noninertial frame.

Doing it correctly is not at all difficult, although it involves a short calculation with the Dirac Equation. The QM book by Shiff has a good one-page derivation.
 

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