Dissolution of Inconel 617/Haynes 230

  • Thread starter Thread starter rams210405
  • Start date Start date
Click For Summary
SUMMARY

The discussion focuses on the challenges of dissolving nickel-based alloys Inconel 617 and Haynes 230 for precipitate analysis using X-ray diffraction (XRD). The Berzelius solution, consisting of copper (II) chloride, potassium chloride, tartaric acid, distilled water, and hydrochloric acid, proved ineffective for these alloys. The alloys exhibit resistance to halogen acids and oxidative conditions, complicating dissolution efforts. A potential method involves using a reductive environment with hot carbon monoxide, although this may lead to alloy destruction rather than recovery of its elements.

PREREQUISITES
  • Understanding of nickel-based alloys, specifically Inconel 617 and Haynes 230
  • Familiarity with X-ray diffraction (XRD) techniques for precipitate analysis
  • Knowledge of chemical solutions used for metal dissolution, particularly the Berzelius solution
  • Awareness of corrosion resistance properties of alloys in oxidative and reductive environments
NEXT STEPS
  • Research alternative chemical solutions for dissolving nickel-based alloys
  • Explore the use of hot carbon monoxide for metal dissolution and its implications
  • Investigate the corrosivity charts in Perry's Chemical Engineering Handbook for effective dissolution methods
  • Study the effects of halogen acids on Inconel and Haynes alloys under various conditions
USEFUL FOR

Materials scientists, metallurgists, and researchers involved in the analysis of nickel-based alloys and their dissolution processes.

rams210405
Messages
2
Reaction score
0
I am trying to dissolve the nickel-based alloys Inconel 617 and Haynes 230 in order to analyze the precipitates with XRD. I already tried the Berzelius solution which is 47.7 g of copper (II) chloride, 41.7 g of potassium chloride, 2.9 g of tartaric acid, 275 ml of distilled water, and 22.4 ml of hydrochloric acid. While this worked for several steels it had almost no effect on the nickel alloys. If you have any ideas on what might work please help!
 
Chemistry news on Phys.org
If you have access to Perry's Chemical Engineering Handbook, you can find some of these exotic alloys and their corrosivity charts to many chemicals under a number of conditions. The inconels and Haynes alloys are made for Halogen acid resistance and are also resistant to oxidative conditions. The solution you are using is made to apply oxidative Cl- attack and keep the metal ions in chelated solution.

A reductive (hot CO) can remove Ni as the poisonous Nickel Carbonyl gas and leave the alloy largely destroyed or embrittled. If the goal is recovery of the elements of the alloy this won't work, but there may be some combo that will achieve a similar chemical route to corroding the metal in a quantitative manner.
 

Similar threads

  • · Replies 8 ·
Replies
8
Views
8K
  • · Replies 1 ·
Replies
1
Views
8K