Drop in Concentration as reaction progresses

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Discussion Overview

The discussion revolves around an investigation into the reaction between different acids and magnesium metal, specifically focusing on how the concentration of acid changes as the reaction progresses. The scope includes experimental design and analysis related to chemical reactions.

Discussion Character

  • Experimental/applied, Homework-related

Main Points Raised

  • One participant suggests measuring the concentration drop by removing aliquots of the solution at various intervals and titrating the acid to plot concentration against time.
  • Another participant reports calculating the number of moles of HCl and H+ ions, noting a percentage drop in concentration.
  • A participant mentions that the maximum theoretical drop in concentration is 5.20% for a concentration of 0.8 M, indicating that this drop may not be significant.
  • It is noted that the shrinking surface area of the magnesium metal during the reaction could affect the reaction rate, potentially leading to changes in concentration over time.

Areas of Agreement / Disagreement

Participants express varying views on the significance of the concentration drop, with some indicating it may not be substantial while others highlight factors that could influence the reaction rate. The discussion remains unresolved regarding the implications of these observations.

Contextual Notes

Limitations include assumptions about the reaction conditions, the dependence on the definitions of significant concentration changes, and the potential impact of surface area on reaction rates, which are not fully explored.

jaz1409
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Homework Statement



I am currently doing an investigation into the reaction between different acids and magnesium metal. I want to try and show that by using a large volume of acid the concentration drop as the reaction progresses is significantly reduced. Is there any way of doing this?


Homework Equations



Mg (s) + 2 HCl (aq) --> H2 (g) + MgCl2 (aq)
Mg (s) + 2 H+ (aq) --> H2 (g) + Mg+2 (aq)

The Attempt at a Solution



Well I thought that by working out the moles of H+ ions present at the beginning of the reaction and at the end of the reaction may help. Other than that, I would just like to be pointed in the right direction.
 
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You could remove an aliquot of solution at several intervals and titrate the acid. Plot the concentration of acid vs time for your result.

The results might surprise you, though...
 
well, so far I have found out the number of moles of HCL in 100cm3 of acid and then found the number of moles of H+ ions. I then found the percentage drop.
 
What did you notice about the reaction rate?
 
well, I worked out that the maximum drop in concentration theoretically was 5.20% which for a concentration of 0.8 M is not significant.
 
Thats what I thought would happen. Also, the metal surface area is shrinking during the reaction. This will cause the greatest change in rate of reaction.
 

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