Enthalpy: A Measure of Total Energy in a System

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SUMMARY

Enthalpy is defined as a measure of the total energy of a thermodynamic system, encompassing both internal energy and the energy required to displace the environment to establish volume and pressure. The discussion highlights confusion surrounding this definition, particularly regarding how internal energy contributes to the creation of a system. The concept of standard enthalpy of formation is introduced, which refers to the energy needed to combine elements into a substance. This clarification is essential for understanding enthalpy in the context of chemistry.

PREREQUISITES
  • Understanding of thermodynamic systems
  • Familiarity with internal energy concepts
  • Knowledge of standard enthalpy of formation
  • Basic principles of chemistry
NEXT STEPS
  • Research the concept of "enthalpy of formation" in detail
  • Explore the relationship between enthalpy and internal energy
  • Study the applications of enthalpy in chemical reactions
  • Learn about different types of enthalpy changes, such as enthalpy of vaporization and enthalpy of fusion
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Chemistry students, educators, and professionals in thermodynamics or physical chemistry seeking to clarify the concept of enthalpy and its applications in various chemical processes.

boobybobble
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Hi, i was studying about enthalpy earlier and found its definition to be confusing

"Enthalpy is a measure of the total energy of a thermodynamic system. It includes the internal energy, which is the energy required to create a system, and the amount of energy required to make room for it by displacing its environment and establishing its volume and pressure. "

i don't understand the italicized part...how can internal energy create a system?? :confused:
 
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Hello boobybobble, welcome to Physics Forums.

Your definition of enthalpy was a bit unusual, where did it come from?

In respect of your actual question this probably refers to the use of enthalpy in chemistry where there is a standard enthalpy of formation for every substance.
This is the energy required to combine the various constituent elements to form the substance.

http://en.wikipedia.org/wiki/Standard_enthalpy_of_formation

go well
 
Studiot said:
Hello boobybobble, welcome to Physics Forums.

Your definition of enthalpy was a bit unusual, where did it come from?

In respect of your actual question this probably refers to the use of enthalpy in chemistry where there is a standard enthalpy of formation for every substance.
This is the energy required to combine the various constituent elements to form the substance.

http://en.wikipedia.org/wiki/Standard_enthalpy_of_formation

go well

thanks Studiot :smile:

http://en.wikipedia.org/wiki/Enthalpy -->thats where i got the definition from

As for the link you posted, it elaborates on "enthalpy of formation", which is something like enthalpy of -evaporation condensation and blah blah...but I'm talking about the entity enthalpy itself, which is pretty confusing given the definition in wikipedia and a lot of other websites(and my book too).
 

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