Expectation value of momentum for free particle

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Discussion Overview

The discussion centers around the computation of the expectation value of momentum for a free particle, specifically in the context of monochromatic waves and Gaussian wave packets. Participants explore the implications of different wave functions on the expectation value and the conditions under which these calculations can be performed.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant inquires about calculating the expectation value of momentum for a free particle using a monochromatic wave, noting that their integral yields infinity.
  • Another participant states that the result depends on the state used for the computation, indicating that a Gaussian state yields a finite result.
  • A participant emphasizes that for an unnormalizable wave function like |k⟩, expectation values cannot be discussed or computed.
  • There is a question regarding Wikipedia's claim that the expectation value can be computed as ℏk, despite the challenges with unnormalizable wave functions.
  • It is suggested that expectation values should be calculated for wave packets, such as Gaussian functions, and then limits should be taken regarding position and momentum spreads.
  • A participant discusses the properties of a Gaussian wave packet, stating that it approaches a plane wave in the limit of infinite variance and provides a specific form of the wave function that yields the momentum expectation value ℏk.

Areas of Agreement / Disagreement

Participants express differing views on the validity of calculating expectation values for monochromatic waves versus Gaussian wave packets. There is no consensus on the implications of Wikipedia's statement regarding the expectation value.

Contextual Notes

The discussion highlights limitations related to the normalization of wave functions and the conditions under which expectation values can be computed. The dependence on the choice of wave function is a key point of contention.

Joker93
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Hello!
Could somebody please tell me how i can compute the expectation value of the momentum in the case of a free particle(monochromatic wave)? When i take the integral, i get infinity, but i have seen somewhere that we know how much the particle's velocity is, so i thought that we can get it from the expectation value of its momentum.

Also, Wikipedia states(here: https://en.wikipedia.org/wiki/Free_particle#Measurement_and_calculations -- just scroll down a bit) that one CAN do the calculation via the integral and get hbar*k.

Thanks!
 
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The result depends on the state in which you compute the expectation. In a Gaussian state the result is finite.
 
A. Neumaier said:
The result depends on the state in which you compute the expectation. In a Gaussian state the result is finite.
Hello! No, no, i am talking about a monochromatic wave(single k).
 
Adam Landos said:
Hello! No, no, i am talking about a monochromatic wave(single k).
For an unnormalizable wave function such as ##|k\rangle## you cannot talk about expectations, let alone compute them!
 
A. Neumaier said:
For an unnormalizable wave function such as ##|k\rangle## you cannot talk about expectations, let alone compute them!
So, why does Wikipedia(the link i have provided) state that it is hbar*k?
 
Adam Landos said:
So, why does Wikipedia(the link i have provided) state that it is hbar*k?
You must calculate the expectation for wave packets (such as Gaussians), and then take the limit of infinite spread in position, and zero spread in momentum.
 
A. Neumaier said:
You must calculate the expectation for wave packets (such as Gaussians), and then take the limit of infinite spread in position, and zero spread in momentum.
Gaussian with infinity variance gives a plane wave or a constant(in space) function?
 
Adam Landos said:
Gaussian with infinity variance gives a plane wave or a constant(in space) function?
##\psi(x)=e^{\pm ik\cdot x-x^2/2\sigma^2}## gives (after normalization, and with the correct sign) a moving Gaussian wave packet with momentum ##\langle p\rangle=\hbar k## and approaches a plane wave in the limit ##\sigma\to\infty##
 
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A. Neumaier said:
##\psi(x)=e^{\pm ik\cdot x-x^2/2\sigma^2}## gives (after normalization, and with the correct sign) a moving Gaussian wave packet with momentum ##\langle p\rangle=\hbar k## and approaches a plane wave in the limit ##\sigma\to\infty##
Thanks!
 

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