Finding pH of a buffer with polyprotic acid

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    Acid Buffer Ph
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SUMMARY

The discussion focuses on calculating the pH of a buffer solution created by mixing 0.30 mol NaOH, 0.25 mol Na2HPO4, and 0.20 mol H3PO4 in 1.00L of water. Participants emphasize the importance of using the Henderson-Hasselbalch equation and correctly identifying the limiting reagents in the reaction. The primary acid, H3PO4, reacts first with the strong base NaOH, and the resulting concentrations of the conjugate acid (H2PO4-) and conjugate base (HPO4^2-) are critical for accurate pH calculation. The final pH is determined by the ratio of these species, highlighting the necessity of considering all components in the buffer system.

PREREQUISITES
  • Understanding of acid-base reactions, particularly with polyprotic acids.
  • Familiarity with the Henderson-Hasselbalch equation.
  • Knowledge of molarity and how to calculate concentrations from moles.
  • Basic principles of limiting reagents in chemical reactions.
NEXT STEPS
  • Study the Henderson-Hasselbalch equation in detail to understand its application in buffer solutions.
  • Learn about the properties and behavior of polyprotic acids, specifically phosphoric acid.
  • Explore the concept of limiting reagents and how they affect reaction outcomes.
  • Practice calculating pH for various buffer systems using different concentrations and components.
USEFUL FOR

Chemistry students, laboratory technicians, and anyone involved in buffer solution preparation and pH calculations, particularly in biochemical and analytical contexts.

  • #31
Wow, thanks! Hahaha, that was the most frustrating problem I've dealt with in a while, but it feels very good to have gotten through it. Thanks for all the help!
 

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