Gibb's Free Energy: Spontaneous Reactions at High Temperatures

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SUMMARY

The discussion centers on the implications of Gibb's Free Energy in determining the spontaneity of chemical reactions at extreme temperatures. The formula Delta G = Delta H - (T*Delta S) is applied to the reaction H2O(g) C(s) --> CO(g) + H2(g), where Delta H is 135.5 kJ and Delta S is 0.1488 kJ. At 1173 Kelvin, the calculated Delta G is -39, indicating spontaneity. However, the discussion concludes that while theoretically possible, reactions at impractical temperatures, such as 999999999999999999999999 degrees Kelvin, lack practical significance due to competing reactions at extreme conditions.

PREREQUISITES
  • Understanding of Gibb's Free Energy and its components (Delta H, Delta S)
  • Basic knowledge of thermodynamics and reaction spontaneity
  • Familiarity with chemical reaction equations
  • Concept of temperature effects on chemical systems
NEXT STEPS
  • Research the implications of extreme temperatures on chemical reactions
  • Study the relationship between entropy and spontaneity in thermodynamics
  • Explore the limitations of Gibb's Free Energy in practical applications
  • Investigate competing reactions at high temperatures in chemical systems
USEFUL FOR

Chemists, chemical engineers, and students studying thermodynamics and reaction kinetics will benefit from this discussion, particularly those interested in the behavior of reactions under extreme conditions.

rajakavuru
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Hello,
If a reaction is spontaneous when calculated using Gibb's Free Energy formula,
Delta G = Delta H - (T*Delta S)

Does it mean the reaction will occur at impossible temperatures even (such as 999999999999999999999999 degrees Kelvin)

for ex:
H2O(g) C(s) --> CO(g)+H2(g)
Delta H = 135.5 kJ
Delta S = .1488 kJ
T = 1173 Kelvin

Delta G = -39 (if delta G is negative, the reaction is spontanious, according to Gibb's Free Energy)

since this reaction is spontanious, will this occur at 99999999999999999 degrees kelvin even? (is this possible?)
 
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Theoretically, it is. But since you cannot achieve such a temperature, it has no practical significance.
 
No, it doesn't mean that. When temperature rises other effects/reactions tend to take place and they replace initial system.

http://en.wikipedia.org/wiki/Orders_of_magnitude_(temperature )
 
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