Proving E=hf without assumptions is challenging, as the formula is primarily based on experimental evidence rather than classical derivation. It is often treated as an axiom in quantum mechanics, with its validity established through experiments like the photoelectric effect. The relationship between energy and frequency can be derived from light wave behavior, but applying it to matter waves relies on assumptions about their similarity to light. The discussion highlights that many fundamental physics equations, including Newton's laws and Maxwell's equations, also lack derivation from first principles. Ultimately, E=hf serves as a cornerstone of quantum physics, grounded in empirical findings rather than classical derivation.