How Do We Calculate Different Average Diameters of Colloids?

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SUMMARY

The discussion focuses on calculating different average diameters of colloidal spherical polymer particles, specifically the surface average diameter and the volume average diameter. The surface average diameter is calculated using the formula d_s = √(Σ n_i d_i² / Σ n_i), while the volume average diameter is determined using d_v = √(Σ n_i d_i³ / Σ n_i). Given a dispersion with Np = 4•1013 particles/dm3 and a total surface area of 820 m2 in 1 dm3, participants discuss how to derive individual particle dimensions from the total surface area.

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A dispersion of spherical polymer particles contains Np = 4•1013 particles/dm3. The total surface of the particles in 1 dm3 is Asp = 820 m2.

a) What kind of average diameter can we calculate. Calculate this average diameter.

b) If we know that the dispersion contains 60 vol% water, we can calculate another type of average diameter. Which? Find it!


a) Surface average.

[tex]\bar{d_s} = \sqrt{\frac{\Sigma n_i d_i^2}{\Sigma n_i}}[/tex]

b) Volume average.

[tex]\bar{d_s} = \sqrt{\frac{\Sigma n_i d_i^3}{\Sigma n_i}}[/tex]

I don't know how to incorporate the data into the formulas.
 
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Can't you just work it out by taking the surface area of a sphere and working back to get the radius?

You know the total surface area of the total particles in 1 litre, and you know how many particles there are in 1 litre, so from that you can work out the surface area of 1 particle.
 

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