How do we know a state function will stay normalized?

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Discussion Overview

The discussion centers on the question of whether a state function, once normalized, will remain normalized over time according to the Schrödinger Equation. Participants explore theoretical aspects, mathematical reasoning, and implications related to quantum mechanics.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant questions how normalization of a state function is maintained over time, referencing the time-dependent nature of the Schrödinger Equation.
  • Another participant suggests that the logical basis for normalization is tied to the conservation of matter, implying that a normalized wave function reflects the probability of finding a particle in the universe.
  • A different viewpoint highlights that the evolution of the wave function under the Schrödinger Equation is a unitary transformation, which preserves normalization if the initial wave function is normalized.
  • One participant proposes examining the time derivative of the product of the wave function and its complex conjugate to demonstrate normalization over time.
  • Another contribution discusses the general solution to the Schrödinger Equation and the implications of the Born interpretation for time-dependent probability density, suggesting that normalization constants may also vary with time.
  • One participant presents a mathematical expression indicating that the inner product of the wave function remains constant over time, implying normalization is preserved.
  • Another participant asserts that the unitarity of the evolution operator ensures normalization is maintained, referencing the hermitian nature of the Hamiltonian.

Areas of Agreement / Disagreement

Participants present multiple competing views on the topic, with some arguing for the preservation of normalization through unitary evolution and others questioning the implications of measurement and time dependence. The discussion remains unresolved regarding the specifics of how normalization is maintained in all contexts.

Contextual Notes

Some participants reference mathematical proofs and concepts that may depend on specific assumptions or definitions related to quantum mechanics, which are not fully elaborated in the discussion.

esradw
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According to Shrodinger Equation, The state function must change with time, soI wonder how do we know that after we normalize this state function, it will stay normalized ?

Thanks
 
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I don't remember the actual proof, but the notion that the wave function must stay normalized is fairly logical.

Think of it this way... in a non relativistic process matter must be conserved... The fact that the wave function is normalized means that there is a probability to observe the particle somewhere in the universe. Given that it's here one minute (ie in our universe) we would expect it to remain within our observable universe in the next.

All it's saying is that particles don't suddenly disappear.

I believe griffith's intro to QM has the actual proof.
 
Schrödinger's equation can be expressed as an unitary transform from a state a t=0 to a state t=t' and unitary transforms leave the inner product of wavefunctions unchanged. So if the initial wave function was normalized then evolution under the Schrödinger equation will lead to another wavefunction which is also normalized.

This is not true for the process of measurement since it cannot be represented by a unitary transform.
 
Consider \frac{d}{dt}\left(\psi\psi^{\ast}\right) using Schrödinger's Equation and if memory serves it drops out fairly easily.
 
This is just a copy/paste of post I made in another thread..

When solving the SE by the method of separation of variables, we find that the time dependent part of the solution is \exp{iEt/\hbar}, and the position dependent part satisfies the time-dependent SE. Denote \psi(x) the solution to the time dependent SE for a given potential. Then the general solution to the SE is \Psi(x,t)=\psi(x)e^{iEt/\hbar}, and according to the Born interpretation, \Psi \Psi^* is a probability density function for the position of the particle. But \Psi \Psi^* = \psi\psi^*. I.e. the probability density is is time dependent!

From there, showing that the normalisation constant is time-dependent is just one step away.
 
\frac{d}{dt}\left(\langle \psi(t),\psi(t)\rangle\right) =0 \Leftrightarrow \frac{d\psi(t)}{dt}=\frac{1}{i\hbar}\hat{H}\psi(t) \ ,\ \forall \psi(t)\in D(\hat{H})

Daniel.
 
The normalisation remains because of the unitarity of the evolution operator.
The operator U = exp(H t /i hbar) preserves the normalisation because H is hermitian.
This is easy to check by developping
<phi(t)|phi(t)> = <phi(0)|Ut U|phi(o)>​
for small time steps.
Therefore is applies also for time-dependent hamiltonians.

Michel
 
Last edited:

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