How Does Electron Flow Work in a Zn-Cu Electrochemical Cell?

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Discussion Overview

The discussion revolves around the electron flow in a Zn-Cu electrochemical cell, focusing on the chemical reaction, the roles of the anode and cathode, and the identification of oxidizing and reducing agents. It includes aspects of homework-related questions and technical explanations of electrochemical processes.

Discussion Character

  • Homework-related, Technical explanation, Debate/contested

Main Points Raised

  • One participant states that 2 moles of electrons are transferred from zinc to copper, identifying zinc as the anode and copper as the cathode.
  • Another participant confirms the half-reactions and reiterates that electrons flow from zinc to copper, asserting that copper is the oxidizing agent.
  • A suggestion is made to consult the reactivity series for further clarification.
  • A later reply expresses gratitude and suggests that the professor's assertion about the direction of electron flow and the identity of the oxidizing agent may be incorrect.

Areas of Agreement / Disagreement

Participants express disagreement regarding the direction of electron flow and the identification of the oxidizing agent, with some supporting the initial participant's claims and others referencing the professor's perspective.

Contextual Notes

There are unresolved assumptions regarding the definitions of oxidizing and reducing agents, as well as the interpretation of the electrochemical cell's operation. The discussion does not reach a consensus on these points.

Who May Find This Useful

This discussion may be useful for students studying electrochemistry, particularly those working on homework related to electrochemical cells and the flow of electrons in redox reactions.

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Homework Statement




2. Consider an electrochemical cell as shown, with Zn in ZnCl2(aq) and Cu in Cu(NO3)2(aq), and a salt bridge containing KNO3(aq). The overall chemical reaction is
Zn(s) + Cu2+(aq)  Zn2+(aq) + Cu(s).

a. How many moles of electrons are transferred in this reaction?
b. Which side is the anode?.
c. Which direction will electrons travel?
d. Which material is being reduced?
e. What is the oxidizing agent?


Homework Equations



a for a i understand that 2 moles of electrons are transferred through the salt brige. From anode to cathode.for b i said that the left side is the anode and c) that the electrons travel from zinc to copper
for d: o recognize that Cu 2+ is being reduced because it gains 2 electrons and becomes Cu (s). for e i think that since Cu 3+ is rduced it is the oxidizing agent..


The Attempt at a Solution




but my professor says the electrons flow from copper to zinc andthat zinc is the oxidizing agent...can anyone explain?
 
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Write the half reactions:Zn \rightarrow Zn^{2+} + 2e^{-}Cu^{2+} + 2e^{-} \rightarrow Cu

The electrons flow from zinc to copper and copper is the oxidizing agent.
 
Last edited:
Google reactivity series.
 
thanx so i guess my prof was wrong thanx
 

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