How Does Temperature Influence Voltage in Electrochemical Cells?

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SUMMARY

The discussion centers on the influence of temperature on voltage in electrochemical cells, specifically in standard 1 M solutions. The Nernst equation, Ecell=E°cell- (RT/nF) lnQ, is pivotal in understanding this relationship. Experimental results indicated a voltage increase of 0.012 V per Kelvin, although the conditions were not ideal, leading to skepticism about the accuracy. Theoretical implications suggest that while increased temperature should enhance reaction rates, it may also lead to a decrease in voltage due to the behavior of the cathode and anode reactions.

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Homework Statement


Determine the affect of temperature on voltage on an electrochemical cell in standard 1 M solutions.


Homework Equations



Only equation in high school chem: Ne=It/F

This Nernst equation keeps on coming up even though we haven't learned it in class.

Ecell=E°cell- (RT/nF) lnQ.


The Attempt at a Solution



Our high school class did 6 experiments and we came up with the conclusion that the voltage increases .012 V/k. The High school lab conditions weren't ideal and I don't really trust the results.I'm all confused now.

Pratically, as temperature increases the reaction rate should increases. This is why car batteries have trouble starting in winter and people keep batteries in the fridge.

Theoretically, as temperature increase, the voltage should drop based upon Nernst. The non-sportaneous reaction of the cathode oxidizing will happen more readily and counteract the oxidation of the anode.

Help is much appreciated.
 
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Hockeystar said:
Ecell=E°cell- (RT/nF) lnQ.

Under what conditions is lnQ positive, and under what conditions is it negative?
 
Ahh I got it. Seems like the aluminum solution was off in class and that's why it has the biggest rate of change.
 

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