How Much Propylmagnesium Bromide is Needed for This Grignard Reaction?

Click For Summary
SUMMARY

The discussion focuses on calculating the amount of a 0.50M solution of propylmagnesium bromide required to react with 25g of a starting material in a Grignard reaction, factoring in a 15% excess of the reagent and a predicted 78% yield of the product. Participants emphasize the importance of understanding the molar ratio between butenal and propylmagnesium bromide to balance the reaction correctly. The initial challenge lies in balancing the chemical equation, particularly with the inclusion of H3O+, which is not essential for the stoichiometric calculations.

PREREQUISITES
  • Understanding of Grignard reactions
  • Knowledge of stoichiometry and molar ratios
  • Familiarity with dimensional analysis
  • Basic principles of chemical reaction balancing
NEXT STEPS
  • Study the mechanism of Grignard reactions
  • Learn how to calculate stoichiometric coefficients in chemical equations
  • Explore dimensional analysis techniques for chemistry
  • Investigate yield calculations and their impact on product predictions
USEFUL FOR

Organic chemistry students, particularly those studying Grignard reactions, and anyone needing to understand stoichiometric calculations in chemical reactions.

ampersand15
Messages
1
Reaction score
0
I'm in organic chemistry 1. We haven't gone over the Grignard reaction in class, but there was a stoichiometry problem assigned about one and I don't know how to get it started.

Homework Statement



The following Grignard reaction is performed.

RsxY7.jpg


Calculate how much of a 0.50M solution of propylmagnesium bromide is required to react completely with 25g of the starting material. Assume you need a 15% excess of the Grignard reagent. Then predict the amount of product based upon a 78% yield.


Homework Equations



If I can get past the first step it's just dimensional analysis.

The Attempt at a Solution



I'm having trouble at the first step, balancing the reaction. I end up with 7C, 16H, 2O, 1Mg, 1Br on the reactant side, and 7C, 14H, 2O, 1Mg, and 1Br on the product side. The only thing I can do that balances the equation is to ignore the H3O+. Is this what I'm supposed to do? Not including H3O+ in the calculation leaves me with 7C, 13H, and 1O on both sides. I'm assuming this has something to do with the Grignard reaction that I haven't encountered yet?

Thanks
 
Physics news on Phys.org
Don't worry too much about exact reaction. First of all, check how the Grignard reagent works. The only information you need to solve is the molar ratio between butenal and propylmagnesium bromide.
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 2 ·
Replies
2
Views
4K
  • · Replies 16 ·
Replies
16
Views
6K
Replies
8
Views
6K
  • · Replies 10 ·
Replies
10
Views
22K
  • · Replies 4 ·
Replies
4
Views
3K
Replies
1
Views
6K