Identifying an element from Emission Spectrum

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SUMMARY

The discussion centers on identifying elements from emission spectra using data collected from a spectrometer with a 100 lines/mm diffraction grating. The user has calculated wavelengths for the 1st and 2nd order lines of Blue/Violet, Green, and Orange colors but struggles to correlate these wavelengths with known emission spectra to identify the element. The user questions whether the spectrometer's resolution is inadequate and seeks a definitive method to match their calculated wavelengths with established spectral data, specifically referencing nitrogen.

PREREQUISITES
  • Understanding of emission spectra and spectral lines
  • Familiarity with spectrometer operation and resolution
  • Knowledge of wavelength measurement techniques
  • Ability to interpret spectral data tables
NEXT STEPS
  • Research methods for correlating calculated wavelengths with known emission spectra
  • Learn about the resolution limits of spectrometers and their impact on spectral identification
  • Explore databases of emission spectra, such as the NIST Atomic Spectra Database
  • Investigate techniques for enhancing spectrometer resolution and accuracy
USEFUL FOR

Students and researchers in physics and chemistry, particularly those involved in spectroscopy, laboratory analysis, and elemental identification using emission spectra.

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Using data collected from a spectrometer, with a diffraction grating of 100 lines/mm, I have collected a set of data. From this I have calculated wavelengths for the 1st and 2nd order lines of the three brightest visible colors, which were Blue/Violet, Green, and Orange.

To complete my lab I am required to identify the element that produced the emission spectrum, however I am really unclear how to go about this.

So, I am left with wavelengths for 1st and 2nd order lines of each color, I've tried to compare this to lists of wavelengths for various emission spectrums I've found, but I see no way to take these wavelengths and positively identify my element. Most lists of wavelengths I find fall within the same range. What is the clear cut method that I am missing to correlate my wavelengths to another set given so as to identify my element?
 
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is the spectrometer's resolution too poor or something? in general one should be able to identify elements pretty easily.
 
inha said:
is the spectrometer's resolution too poor or something? in general one should be able to identify elements pretty easily.
I can't really find any wavelengths to compare my calculated wavelengths to, just pictures of spectra, you can't make a positive id on that.

e.g.

I have a blue/violet 1st order to the right of center, wave length=348.99, and to the left of center=523.359.
Looking at this list:http://physics.nist.gov/PhysRefData/Handbook/Tables/nitrogentable2.htm for nitrogen, how can I even relate my 1st and second order measurements to the nitrogen table?
 
Last edited:

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