If <p> = 0 how can we know the energy of the system

  • Context: Graduate 
  • Thread starter Thread starter talabax
  • Start date Start date
  • Tags Tags
    Energy System
Click For Summary

Discussion Overview

The discussion revolves around the relationship between momentum and energy in quantum mechanics, particularly in stationary states where the expectation value of momentum is zero. Participants explore how energy can be defined in such cases and the implications of average momentum and kinetic energy.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants note that the expectation value of momentum

    can be zero in stationary states, raising questions about how energy can still be defined in the system.

  • Others clarify that the possible energies are determined by the Hamiltonian Hψ = Eψ, which includes both kinetic and potential energy terms.
  • One participant questions the relevance of kinetic energy in the Hamiltonian if

    is zero.

  • Another participant explains that zero average momentum does not imply zero average kinetic energy, as kinetic energy is related to , not

    itself.

  • A later reply uses a classical analogy of gas particles in a box to illustrate that even with zero average momentum, individual particles can still possess positive kinetic energy.

Areas of Agreement / Disagreement

Participants express differing views on the implications of zero average momentum for kinetic energy and energy definitions, indicating that multiple competing views remain without consensus.

Contextual Notes

Some discussions hinge on the interpretation of quantum mechanical operators and their relationships, particularly regarding the definitions and implications of average values in different states.

talabax
Messages
8
Reaction score
0
So when doing the expectation value of <p> on a stationary state we get a 0 and I've seen the standard proof showing why as well as for <p^2> not being 0. But how can momentum be 0 and
yet have a energy defined for the system? Is the energy only due to Vψ = Eψ
 
Physics news on Phys.org
The possible energies are not given by Vψ = Eψ. They are given by Hψ = Eψ, and H = p2/2m + V.
 
but if <p> is 0 how can we have a kinetic energy involved why even have it in the hamiltonian?
 
The Hamiltonian (together with the possible states of the system) is the fundamental description of the system. The Hamiltonian describes how any given state of the system evolves in time.

For any given state ψ, the average value of an observable A in that state is <ψ|A|ψ>.
If you are interested in the average momentum of the state then you choose A = p.
If you are interested in the average kinetic energy of the state then you choose A = p2/2m.
If you are interested in the average energy of the state then you choose A = H, because H is the energy operator, and also called the Hamiltonian.

So although some states have zero average momentum, it doesn't mean that all states have zero average momentum.
 
If the particle spends half the time moving to the left and half the time moving to the right <p> will be zero. This doesn't mean that <|p|> is zero.
 
talabax said:
So when doing the expectation value of <p> on a stationary state we get a 0 and I've seen the standard proof showing why as well as for <p^2> not being 0. But how can momentum be 0 and
yet have a energy defined for the system? Is the energy only due to Vψ = Eψ

If you understand that <p^2> does not necessarily equal zero, then you should be able to understand that <KE> does not necessarily equal zero, since the two are related by a constant (1/2m).
 
talabax said:
So when doing the expectation value of <p> on a stationary state we get a 0 and I've seen the standard proof showing why as well as for <p^2> not being 0. But how can momentum be 0 and
yet have a energy defined for the system? Is the energy only due to Vψ = Eψ
Average kinetic energy is proportional to <p^2>, not to <p>^2.

In fact, you can understand it even with classical statistical physics. Suppose that you have a gas made of classical particles. The gas is in a box at rest. At any given moment of time, some particle move to the left inside the box, while other particles move to the right. In other words, some particles have positive momentum while other particles have negative momentum, so that the average momentum is zero. Nevertheless, each of these particles has a positive kinetic energy, so the average kinetic energy is positive too.
 

Similar threads

  • · Replies 9 ·
Replies
9
Views
2K
  • · Replies 0 ·
Replies
0
Views
1K
  • · Replies 8 ·
Replies
8
Views
1K
  • · Replies 15 ·
Replies
15
Views
2K
  • · Replies 15 ·
Replies
15
Views
3K
  • · Replies 5 ·
Replies
5
Views
1K
  • · Replies 13 ·
Replies
13
Views
2K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 14 ·
Replies
14
Views
2K